Metallocene polymerization with reactive chain transfer agent: synthesis of telechelic polyolefin and functional polyolefin diblock copolymers

Guangxue Xu, J. Y. Dong, Tze-chiang Chung

Research output: Contribution to journalConference article

4 Citations (Scopus)

Abstract

A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.

Original languageEnglish (US)
Number of pages1
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume41
Issue number2
StatePublished - Aug 1 2000
EventWashington,DC. Meeting - Washington, DC, USA
Duration: Aug 20 2000Aug 24 2000

Fingerprint

Polyolefins
Boranes
Block copolymers
Polymerization
Alkenes
Olefins
Polymers
PL 732
metallocene

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

Cite this

@article{65fb3f34848941d1817d487163f2bc82,
title = "Metallocene polymerization with reactive chain transfer agent: synthesis of telechelic polyolefin and functional polyolefin diblock copolymers",
abstract = "A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.",
author = "Guangxue Xu and Dong, {J. Y.} and Tze-chiang Chung",
year = "2000",
month = "8",
day = "1",
language = "English (US)",
volume = "41",
journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",
issn = "0032-3934",
number = "2",

}

TY - JOUR

T1 - Metallocene polymerization with reactive chain transfer agent

T2 - synthesis of telechelic polyolefin and functional polyolefin diblock copolymers

AU - Xu, Guangxue

AU - Dong, J. Y.

AU - Chung, Tze-chiang

PY - 2000/8/1

Y1 - 2000/8/1

N2 - A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.

AB - A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.

UR - http://www.scopus.com/inward/record.url?scp=0038096520&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0038096520&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0038096520

VL - 41

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

SN - 0032-3934

IS - 2

ER -