Abstract
A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1926 |
| Number of pages | 1 |
| Journal | American Chemical Society, Polymer Preprints, Division of Polymer Chemistry |
| Volume | 41 |
| Issue number | 2 |
| State | Published - Aug 2000 |
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All Science Journal Classification (ASJC) codes
- Polymers and Plastics
Cite this
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Metallocene polymerization with reactive chain transfer agent : synthesis of telechelic polyolefin and functional polyolefin diblock copolymers. / Xu, Guangxue; Dong, J. Y.; Chung, Tze-chiang.
In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 41, No. 2, 08.2000, p. 1926.Research output: Contribution to journal › Article
TY - JOUR
T1 - Metallocene polymerization with reactive chain transfer agent
T2 - synthesis of telechelic polyolefin and functional polyolefin diblock copolymers
AU - Xu, Guangxue
AU - Dong, J. Y.
AU - Chung, Tze-chiang
PY - 2000/8
Y1 - 2000/8
N2 - A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.
AB - A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.
UR - http://www.scopus.com/inward/record.url?scp=0038096520&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0038096520&partnerID=8YFLogxK
M3 - Article
VL - 41
SP - 1926
JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
SN - 0032-3934
IS - 2
ER -