Metallocene polymerization with reactive chain transfer agent: synthesis of telechelic polyolefin and functional polyolefin diblock copolymers

Guangxue Xu; J. Y. Dong; Tze-chiang Chung

Metallocene polymerization with reactive chain transfer agent: synthesis of telechelic polyolefin and functional polyolefin diblock copolymers

Guangxue Xu, J. Y. Dong, Tze-chiang Chung

Research output: Contribution to journal › Conference article

Abstract

A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.

Original language	English (US)
Number of pages	1
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	41
Issue number	2
State	Published - Aug 1 2000
Event	Washington,DC. Meeting - Washington, DC, USA Duration: Aug 20 2000 → Aug 24 2000

All Science Journal Classification (ASJC) codes

Polymers and Plastics

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Xu, G., Dong, J. Y., & Chung, T. (2000). Metallocene polymerization with reactive chain transfer agent: synthesis of telechelic polyolefin and functional polyolefin diblock copolymers. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 41(2).

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title = "Metallocene polymerization with reactive chain transfer agent: synthesis of telechelic polyolefin and functional polyolefin diblock copolymers",

abstract = "A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.",

author = "Guangxue Xu and Dong, {J. Y.} and Tze-chiang Chung",

year = "2000",

month = aug,

day = "1",

language = "English (US)",

volume = "41",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

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note = "Washington,DC. Meeting ; Conference date: 20-08-2000 Through 24-08-2000",

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TY - JOUR

T1 - Metallocene polymerization with reactive chain transfer agent

T2 - Washington,DC. Meeting

AU - Xu, Guangxue

AU - Dong, J. Y.

AU - Chung, Tze-chiang

PY - 2000/8/1

Y1 - 2000/8/1

N2 - A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.

AB - A new borane (B-H) in situ chain transfer reaction in metallocene-catalyzed olefin polymerization was established. The obtained chemistry provides a convenient and efficient route to prepare borane-terminated polyolefins that are very valuable intermediates for preparing functionalized polyolefins with a polar end group or diblock copolymer containing a polyolefin and functional (polar) polymer segments.

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M3 - Conference article

AN - SCOPUS:0038096520

VL - 41

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

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IS - 2

Y2 - 20 August 2000 through 24 August 2000

ER -