Abstract
Trisubstituted olefins are reactants in template-directed, solid-state [2+2] photocycloaddition reactions. Whereas hydrogen-bond-based templates afford crystalline assemblies with olefins that are photostable, AgI coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 893-898 |
| Number of pages | 6 |
| Journal | ChemPlusChem |
| Volume | 81 |
| Issue number | 8 |
| DOIs | |
| State | Published - Aug 1 2016 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
Cite this
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Metal–Organic Coordination versus Hydrogen Bonding : Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State. / Elacqua, Elizabeth; Sinnwell, Michael A.; Loren, Bradley P.; Jurgens, Paul T.; Groeneman, Ryan H.; Reinheimer, Eric W.; MacGillivray, Leonard R.
In: ChemPlusChem, Vol. 81, No. 8, 01.08.2016, p. 893-898.Research output: Contribution to journal › Article
TY - JOUR
T1 - Metal–Organic Coordination versus Hydrogen Bonding
T2 - Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State
AU - Elacqua, Elizabeth
AU - Sinnwell, Michael A.
AU - Loren, Bradley P.
AU - Jurgens, Paul T.
AU - Groeneman, Ryan H.
AU - Reinheimer, Eric W.
AU - MacGillivray, Leonard R.
PY - 2016/8/1
Y1 - 2016/8/1
N2 - Trisubstituted olefins are reactants in template-directed, solid-state [2+2] photocycloaddition reactions. Whereas hydrogen-bond-based templates afford crystalline assemblies with olefins that are photostable, AgI coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.
AB - Trisubstituted olefins are reactants in template-directed, solid-state [2+2] photocycloaddition reactions. Whereas hydrogen-bond-based templates afford crystalline assemblies with olefins that are photostable, AgI coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.
UR - http://www.scopus.com/inward/record.url?scp=84979746937&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84979746937&partnerID=8YFLogxK
U2 - 10.1002/cplu.201600261
DO - 10.1002/cplu.201600261
M3 - Article
AN - SCOPUS:84979746937
VL - 81
SP - 893
EP - 898
JO - ChemPlusChem
JF - ChemPlusChem
SN - 2192-6506
IS - 8
ER -