Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State

Elizabeth Elacqua, Michael A. Sinnwell, Bradley P. Loren, Paul T. Jurgens, Ryan H. Groeneman, Eric W. Reinheimer, Leonard R. MacGillivray

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Trisubstituted olefins are reactants in template-directed, solid-state [2+2] photocycloaddition reactions. Whereas hydrogen-bond-based templates afford crystalline assemblies with olefins that are photostable, AgI coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.

Original languageEnglish (US)
Pages (from-to)893-898
Number of pages6
JournalChemPlusChem
Volume81
Issue number8
DOIs
StatePublished - Aug 1 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State'. Together they form a unique fingerprint.

Cite this