Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State

Elizabeth Elacqua; Michael A. Sinnwell; Bradley P. Loren; Paul T. Jurgens; Ryan H. Groeneman; Eric W. Reinheimer; Leonard R. MacGillivray

doi:10.1002/cplu.201600261

Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State

Elizabeth Elacqua, Michael A. Sinnwell, Bradley P. Loren, Paul T. Jurgens, Ryan H. Groeneman, Eric W. Reinheimer, Leonard R. MacGillivray

Chemistry

Research output: Contribution to journal › Article

4 Scopus citations

Abstract

Trisubstituted olefins are reactants in template-directed, solid-state [2+2] photocycloaddition reactions. Whereas hydrogen-bond-based templates afford crystalline assemblies with olefins that are photostable, Ag^I coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.

Original language	English (US)
Pages (from-to)	893-898
Number of pages	6
Journal	ChemPlusChem
Volume	81
Issue number	8
DOIs	https://doi.org/10.1002/cplu.201600261
Publication status	Published - Aug 1 2016

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All Science Journal Classification (ASJC) codes

Chemistry(all)

Cite this

Elacqua, E., Sinnwell, M. A., Loren, B. P., Jurgens, P. T., Groeneman, R. H., Reinheimer, E. W., & MacGillivray, L. R. (2016). Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State. ChemPlusChem, 81(8), 893-898. https://doi.org/10.1002/cplu.201600261

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Metal–Organic Coordination versus Hydrogen Bonding : Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State. / Elacqua, Elizabeth; Sinnwell, Michael A.; Loren, Bradley P.; Jurgens, Paul T.; Groeneman, Ryan H.; Reinheimer, Eric W.; MacGillivray, Leonard R.

In: ChemPlusChem, Vol. 81, No. 8, 01.08.2016, p. 893-898.

Research output: Contribution to journal › Article

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10.1002/cplu.201600261