Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State

Elizabeth Elacqua, Michael A. Sinnwell, Bradley P. Loren, Paul T. Jurgens, Ryan H. Groeneman, Eric W. Reinheimer, Leonard R. MacGillivray

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Trisubstituted olefins are reactants in template-directed, solid-state [2+2] photocycloaddition reactions. Whereas hydrogen-bond-based templates afford crystalline assemblies with olefins that are photostable, AgI coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.

Original languageEnglish (US)
Pages (from-to)893-898
Number of pages6
JournalChemPlusChem
Volume81
Issue number8
DOIs
StatePublished - Aug 1 2016

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Alkenes
Hydrogen bonds
Crystalline materials

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Elacqua, Elizabeth ; Sinnwell, Michael A. ; Loren, Bradley P. ; Jurgens, Paul T. ; Groeneman, Ryan H. ; Reinheimer, Eric W. ; MacGillivray, Leonard R. / Metal–Organic Coordination versus Hydrogen Bonding : Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State. In: ChemPlusChem. 2016 ; Vol. 81, No. 8. pp. 893-898.
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Metal–Organic Coordination versus Hydrogen Bonding : Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State. / Elacqua, Elizabeth; Sinnwell, Michael A.; Loren, Bradley P.; Jurgens, Paul T.; Groeneman, Ryan H.; Reinheimer, Eric W.; MacGillivray, Leonard R.

In: ChemPlusChem, Vol. 81, No. 8, 01.08.2016, p. 893-898.

Research output: Contribution to journalArticle

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