Methylation of biphenyl to 4-methylbiphenyl over NH4F modified nanosized HZSM-C5

Yanan Wang; Xinwen Guo; Chen Zhang; Xiangsheng Wang; Chunshan Song

Methylation of biphenyl to 4-methylbiphenyl over NH₄F modified nanosized HZSM-C5

Yanan Wang, Xinwen Guo, Chen Zhang, Xiangsheng Wang, Chunshan Song

Research output: Contribution to journal › Conference article › peer-review

Abstract

The methylation of biphenyl (BP) with methanol to 4-methylbiphenyl (4-MBP) over NH₄-F modified nanosized HZSM-5 was studied. The effects of reaction conditions were investigated before further study on the modification of catalyst. The reaction temperature had a great influence on the activity and the stability but a little on the selectivity of 4-MBP. The good stability and the high conversion were at 450°C. The effects of NH₄F loading and the calcination temperature of NH₄F modified nanosized HZSM-5 were further investigated. The stability of catalyst is improved greatly with the increase of the NH₄F loading and the calcination temperature, while the selectivity of 4-MBP increased slightly. When the catalyst was calcined at 500°C, the conversion of BP could be kept constant for 10 hr. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

Original language	English (US)
Pages (from-to)	PETR-9
Journal	ACS National Meeting Book of Abstracts
Volume	229
Issue number	2
State	Published - Aug 3 2005
Event	229th ACS National Meeting - San Diego, CA., United States Duration: Mar 13 2005 → Mar 17 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

Cite this

@article{1a0ea166e3d742ac95f0f10d0568689d,

title = "Methylation of biphenyl to 4-methylbiphenyl over NH4F modified nanosized HZSM-C5",

abstract = "The methylation of biphenyl (BP) with methanol to 4-methylbiphenyl (4-MBP) over NH4-F modified nanosized HZSM-5 was studied. The effects of reaction conditions were investigated before further study on the modification of catalyst. The reaction temperature had a great influence on the activity and the stability but a little on the selectivity of 4-MBP. The good stability and the high conversion were at 450°C. The effects of NH4F loading and the calcination temperature of NH4F modified nanosized HZSM-5 were further investigated. The stability of catalyst is improved greatly with the increase of the NH4F loading and the calcination temperature, while the selectivity of 4-MBP increased slightly. When the catalyst was calcined at 500°C, the conversion of BP could be kept constant for 10 hr. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).",

author = "Yanan Wang and Xinwen Guo and Chen Zhang and Xiangsheng Wang and Chunshan Song",

year = "2005",

month = aug,

day = "3",

language = "English (US)",

volume = "229",

pages = "PETR--9",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

number = "2",

note = "229th ACS National Meeting ; Conference date: 13-03-2005 Through 17-03-2005",

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TY - JOUR

T1 - Methylation of biphenyl to 4-methylbiphenyl over NH4F modified nanosized HZSM-C5

AU - Wang, Yanan

AU - Guo, Xinwen

AU - Zhang, Chen

AU - Wang, Xiangsheng

AU - Song, Chunshan

PY - 2005/8/3

Y1 - 2005/8/3

N2 - The methylation of biphenyl (BP) with methanol to 4-methylbiphenyl (4-MBP) over NH4-F modified nanosized HZSM-5 was studied. The effects of reaction conditions were investigated before further study on the modification of catalyst. The reaction temperature had a great influence on the activity and the stability but a little on the selectivity of 4-MBP. The good stability and the high conversion were at 450°C. The effects of NH4F loading and the calcination temperature of NH4F modified nanosized HZSM-5 were further investigated. The stability of catalyst is improved greatly with the increase of the NH4F loading and the calcination temperature, while the selectivity of 4-MBP increased slightly. When the catalyst was calcined at 500°C, the conversion of BP could be kept constant for 10 hr. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

AB - The methylation of biphenyl (BP) with methanol to 4-methylbiphenyl (4-MBP) over NH4-F modified nanosized HZSM-5 was studied. The effects of reaction conditions were investigated before further study on the modification of catalyst. The reaction temperature had a great influence on the activity and the stability but a little on the selectivity of 4-MBP. The good stability and the high conversion were at 450°C. The effects of NH4F loading and the calcination temperature of NH4F modified nanosized HZSM-5 were further investigated. The stability of catalyst is improved greatly with the increase of the NH4F loading and the calcination temperature, while the selectivity of 4-MBP increased slightly. When the catalyst was calcined at 500°C, the conversion of BP could be kept constant for 10 hr. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

UR - http://www.scopus.com/inward/record.url?scp=22744450364&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=22744450364&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:22744450364

SN - 0065-7727

VL - 229

SP - PETR-9

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

IS - 2

T2 - 229th ACS National Meeting

Y2 - 13 March 2005 through 17 March 2005

ER -

Methylation of biphenyl to 4-methylbiphenyl over NH₄F modified nanosized HZSM-C5

Abstract

All Science Journal Classification (ASJC) codes

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