Methylene Chloride Migration in Polycarbonate Packages

Effect of Initial Concentration Profile

Thomas J. Stanley, Montgomery Meigs Alger

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The migration of small molecules out of polymeric food packages into food can be predicted if the important thermodynamic and transport parameters are known. These parameters can be measured in convenient extraction experiments. The surface region of a sample used in extraction testing can be substantially depleted of migrant. When extraction data for a depleted sample are interpreted with respect to a mathematical model which assumes a flat initial migrant concentration profile, the thermodynamic and transport parameters are in error, resulting in an inaccurate prediction of long-time migration behavior. The results presented here demonstrate that even freshly manufactured polymer samples can be substantially surface depleted because migrant diffusion is very rapid at the high temperatures the polymer sees during manufacture.

Original languageEnglish (US)
Pages (from-to)865-869
Number of pages5
JournalIndustrial and Engineering Chemistry Research
Volume28
Issue number6
DOIs
StatePublished - Jun 1 1989

Fingerprint

polycarbonate
Methylene Chloride
Dichloromethane
Polycarbonates
Polymers
Thermodynamics
Mathematical models
Molecules
Testing
Experiments

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

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abstract = "The migration of small molecules out of polymeric food packages into food can be predicted if the important thermodynamic and transport parameters are known. These parameters can be measured in convenient extraction experiments. The surface region of a sample used in extraction testing can be substantially depleted of migrant. When extraction data for a depleted sample are interpreted with respect to a mathematical model which assumes a flat initial migrant concentration profile, the thermodynamic and transport parameters are in error, resulting in an inaccurate prediction of long-time migration behavior. The results presented here demonstrate that even freshly manufactured polymer samples can be substantially surface depleted because migrant diffusion is very rapid at the high temperatures the polymer sees during manufacture.",
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Methylene Chloride Migration in Polycarbonate Packages : Effect of Initial Concentration Profile. / Stanley, Thomas J.; Alger, Montgomery Meigs.

In: Industrial and Engineering Chemistry Research, Vol. 28, No. 6, 01.06.1989, p. 865-869.

Research output: Contribution to journalArticle

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