Abstract
A mathematical model for the cathode of a direct methanol fuel cell (DMFC) is developed to investigate two-phase transport in the catalyst layer (CL) and to elucidate the mechanism of cathode mixed potential due to oxidation of crossover methanol. A coupled model of two-phase species transport and multistep electrochemical kinetics, including simultaneous oxygen reduction, methanol oxidation, and gas phase chemical reaction, is presented. The model predictions agree favorably with experiments of cathode mixed potential, and the predicted profiles of water saturation, oxygen concentration, and overpotential along the CL thickness further reveal the profound interplay between multiple reactions and the transport of oxygen and water. It is shown that in the presence of methanol crossover, the DMFC cathode is operated at higher overpotential and water saturation, with larger oxygen transport loss than that in the H2 /air counterpart. The model results also indicate that reducing the cathode CL thickness can facilitate both liquid water removal and oxygen transport through the CL, leading to improved cathode performance.
| Original language | English (US) |
|---|---|
| Journal | Journal of the Electrochemical Society |
| Volume | 154 |
| Issue number | 6 |
| DOIs | |
| State | Published - Aug 1 2007 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Renewable Energy, Sustainability and the Environment
- Condensed Matter Physics
- Surfaces, Coatings and Films
- Materials Chemistry
- Electrochemistry
Cite this
}
Mixed potential in a direct methanol fuel cell. / Liu, Fuqiang; Wang, Chao-yang.
In: Journal of the Electrochemical Society, Vol. 154, No. 6, 01.08.2007.Research output: Contribution to journal › Article
TY - JOUR
T1 - Mixed potential in a direct methanol fuel cell
AU - Liu, Fuqiang
AU - Wang, Chao-yang
PY - 2007/8/1
Y1 - 2007/8/1
N2 - A mathematical model for the cathode of a direct methanol fuel cell (DMFC) is developed to investigate two-phase transport in the catalyst layer (CL) and to elucidate the mechanism of cathode mixed potential due to oxidation of crossover methanol. A coupled model of two-phase species transport and multistep electrochemical kinetics, including simultaneous oxygen reduction, methanol oxidation, and gas phase chemical reaction, is presented. The model predictions agree favorably with experiments of cathode mixed potential, and the predicted profiles of water saturation, oxygen concentration, and overpotential along the CL thickness further reveal the profound interplay between multiple reactions and the transport of oxygen and water. It is shown that in the presence of methanol crossover, the DMFC cathode is operated at higher overpotential and water saturation, with larger oxygen transport loss than that in the H2 /air counterpart. The model results also indicate that reducing the cathode CL thickness can facilitate both liquid water removal and oxygen transport through the CL, leading to improved cathode performance.
AB - A mathematical model for the cathode of a direct methanol fuel cell (DMFC) is developed to investigate two-phase transport in the catalyst layer (CL) and to elucidate the mechanism of cathode mixed potential due to oxidation of crossover methanol. A coupled model of two-phase species transport and multistep electrochemical kinetics, including simultaneous oxygen reduction, methanol oxidation, and gas phase chemical reaction, is presented. The model predictions agree favorably with experiments of cathode mixed potential, and the predicted profiles of water saturation, oxygen concentration, and overpotential along the CL thickness further reveal the profound interplay between multiple reactions and the transport of oxygen and water. It is shown that in the presence of methanol crossover, the DMFC cathode is operated at higher overpotential and water saturation, with larger oxygen transport loss than that in the H2 /air counterpart. The model results also indicate that reducing the cathode CL thickness can facilitate both liquid water removal and oxygen transport through the CL, leading to improved cathode performance.
UR - http://www.scopus.com/inward/record.url?scp=34547171296&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34547171296&partnerID=8YFLogxK
U2 - 10.1149/1.2718404
DO - 10.1149/1.2718404
M3 - Article
VL - 154
JO - Journal of the Electrochemical Society
JF - Journal of the Electrochemical Society
SN - 0013-4651
IS - 6
ER -