Modeling chemical vapor deposition (CVD) diamond film growth with diamantane-derived radicals in solution: Permissive evidence in support of the Garrison-Brenner mechanism for incorporation of carbon into the dimer sites of the {100} diamond surface

Ken S. Feldman, Robert F. Campbell, Theodore R. West, Allen D. Aloise, David Giampetro

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The synthesis and partial rearrangement of nordiamantanemethyl radical into its more stable diamantyl isomer at 200-300 °C is reported. This solution phase observation attests to the feasibility of similar processes proposed to occur at the surface of {100} diamond film under CVD conditions.

Original languageEnglish (US)
Pages (from-to)7612-7617
Number of pages6
JournalJournal of Organic Chemistry
Volume64
Issue number20
DOIs
StatePublished - Oct 1 1999

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Adamantane
Diamond
Diamond films
Film growth
Isomers
Dimers
Chemical vapor deposition
Carbon

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

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abstract = "The synthesis and partial rearrangement of nordiamantanemethyl radical into its more stable diamantyl isomer at 200-300 °C is reported. This solution phase observation attests to the feasibility of similar processes proposed to occur at the surface of {100} diamond film under CVD conditions.",
author = "Feldman, {Ken S.} and Campbell, {Robert F.} and West, {Theodore R.} and Aloise, {Allen D.} and David Giampetro",
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AU - Feldman, Ken S.

AU - Campbell, Robert F.

AU - West, Theodore R.

AU - Aloise, Allen D.

AU - Giampetro, David

PY - 1999/10/1

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N2 - The synthesis and partial rearrangement of nordiamantanemethyl radical into its more stable diamantyl isomer at 200-300 °C is reported. This solution phase observation attests to the feasibility of similar processes proposed to occur at the surface of {100} diamond film under CVD conditions.

AB - The synthesis and partial rearrangement of nordiamantanemethyl radical into its more stable diamantyl isomer at 200-300 °C is reported. This solution phase observation attests to the feasibility of similar processes proposed to occur at the surface of {100} diamond film under CVD conditions.

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