碱处理调变ZSM-5孔结构及甲苯甲醇烷基化制对二甲苯性能研究

Translated title of the contribution: Modification of ZSM-5 pore structure by alkali treatment and catalytic properties in preparation of p-xylene by alkylation of toluene with methanol

Hong Kun Li, An Feng Zhang, Zhang Gui Hou, Mei Mei Qi, Xiao Guo Li, Yang Chang, Xin Wen Guo, Chun Shan Song

Research output: Contribution to journalArticle

Abstract

Large grain ZSM-5 zeolite is prepared via hydrothermal method. A series of hierarchical porous ZSM-5 catalysts with large grains are obtained by adjusting alkali species and treatment time during alkali treatment. The catalysts are characterized by XRD, SEM, Ar-adsorption and thermogravimetry. Their catalytic performances are evaluated in the selective alkylation of toluene with methanol, and the effects of porous diameter of the catalysts on the conversion rate of toluene and the selectivity of p-xylene are studied. It is found the catalyst that has been treated by 0.2 mol•L-1 of TPAOH solution with a liquid-solid ratio of 30 mL•g-1 at 65℃ for 30 minutes performs the best performance. The average selectivity of p-xylene and the conversion rate of toluene can reach 68.36% and 11.24%, respectively over the optimal catalyst without modification in 30 h, while the carbon deposition rate is only 53% of the parent.

Original languageChinese
Pages (from-to)165-169
Number of pages5
JournalXiandai Huagong/Modern Chemical Industry
Volume39
Issue number10
DOIs
StatePublished - Oct 20 2019

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Alkylation
Toluene
Alkalies
Xylene
Pore structure
Methanol
Catalysts
Deposition rates
Thermogravimetric analysis
Carbon
4-xylene
Adsorption
Scanning electron microscopy
Liquids

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)

Cite this

Li, Hong Kun ; Zhang, An Feng ; Hou, Zhang Gui ; Qi, Mei Mei ; Li, Xiao Guo ; Chang, Yang ; Guo, Xin Wen ; Song, Chun Shan. / 碱处理调变ZSM-5孔结构及甲苯甲醇烷基化制对二甲苯性能研究. In: Xiandai Huagong/Modern Chemical Industry. 2019 ; Vol. 39, No. 10. pp. 165-169.
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abstract = "Large grain ZSM-5 zeolite is prepared via hydrothermal method. A series of hierarchical porous ZSM-5 catalysts with large grains are obtained by adjusting alkali species and treatment time during alkali treatment. The catalysts are characterized by XRD, SEM, Ar-adsorption and thermogravimetry. Their catalytic performances are evaluated in the selective alkylation of toluene with methanol, and the effects of porous diameter of the catalysts on the conversion rate of toluene and the selectivity of p-xylene are studied. It is found the catalyst that has been treated by 0.2 mol•L-1 of TPAOH solution with a liquid-solid ratio of 30 mL•g-1 at 65℃ for 30 minutes performs the best performance. The average selectivity of p-xylene and the conversion rate of toluene can reach 68.36{\%} and 11.24{\%}, respectively over the optimal catalyst without modification in 30 h, while the carbon deposition rate is only 53{\%} of the parent.",
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碱处理调变ZSM-5孔结构及甲苯甲醇烷基化制对二甲苯性能研究. / Li, Hong Kun; Zhang, An Feng; Hou, Zhang Gui; Qi, Mei Mei; Li, Xiao Guo; Chang, Yang; Guo, Xin Wen; Song, Chun Shan.

In: Xiandai Huagong/Modern Chemical Industry, Vol. 39, No. 10, 20.10.2019, p. 165-169.

Research output: Contribution to journalArticle

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AU - Li, Hong Kun

AU - Zhang, An Feng

AU - Hou, Zhang Gui

AU - Qi, Mei Mei

AU - Li, Xiao Guo

AU - Chang, Yang

AU - Guo, Xin Wen

AU - Song, Chun Shan

PY - 2019/10/20

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AB - Large grain ZSM-5 zeolite is prepared via hydrothermal method. A series of hierarchical porous ZSM-5 catalysts with large grains are obtained by adjusting alkali species and treatment time during alkali treatment. The catalysts are characterized by XRD, SEM, Ar-adsorption and thermogravimetry. Their catalytic performances are evaluated in the selective alkylation of toluene with methanol, and the effects of porous diameter of the catalysts on the conversion rate of toluene and the selectivity of p-xylene are studied. It is found the catalyst that has been treated by 0.2 mol•L-1 of TPAOH solution with a liquid-solid ratio of 30 mL•g-1 at 65℃ for 30 minutes performs the best performance. The average selectivity of p-xylene and the conversion rate of toluene can reach 68.36% and 11.24%, respectively over the optimal catalyst without modification in 30 h, while the carbon deposition rate is only 53% of the parent.

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