Modified inductively coupled plasma reactive ion etch process for high aspect ratio etching of fused silica, borosilicate and aluminosilicate glass substrates

Chenchen Zhang, Srinivas A. Tadigadapa

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

We report on the etching of glass substrates of various compositions in a modified inductively coupled plasma – reactive ion etch (ICP-RIE) tool using SF6 as the plasma source gas and NF3 and H2O gases introduced downstream near the surface of the wafer through a diffuser gas inlet. Using this modified system, we have been able to achieve etch rates as high as 1.06 μm/min, 1.04 μm/min, and 0.45 μm/min with surface smoothness of ∼2 Å, ∼67 Å, ∼4 Å for fused silica, borosilicate glass, and aluminosilicate glass respectively after 5 min etches. We examine the role of ion flux and fluorine radicals and molecules on the etch rate and the etch smoothness. We analyze the results obtained on 41 etches through multivariate statistical analysis and use the Pearson coefficient and P-value to determine the importance of these parameters for each of the glass substrate compositions. Overall for all three glass compositions, etch rate is critically influenced by ion flux. Fluorine based radicals and molecular fragments influence both the etch rate and surface smoothness of fused silica whereas they primarily influence the surface smoothness for borosilicate glass. The large fraction of impurity atoms of Ca and Al in aluminosilicate glass form non-volatile fluorides in the etched areas and therefore the etch rate and surface smoothness of aluminosilicate glass is primarily influenced ion flux and very little by the fluorine chemistry. We also examine the role of the layout of the metal mask layer on how it influences the charging of glass substrates during etching and therefore the etch rate.

Original languageEnglish (US)
Pages (from-to)147-158
Number of pages12
JournalSensors and Actuators, A: Physical
Volume273
DOIs
StatePublished - Apr 15 2018

Fingerprint

Aluminosilicates
borosilicate glass
Inductively coupled plasma
Fused silica
high aspect ratio
Aspect ratio
Etching
etching
Ions
silicon dioxide
Glass
glass
Substrates
Fluorine
ions
fluorine
Borosilicate glass
Gases
Fluxes
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Electrical and Electronic Engineering

Cite this

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title = "Modified inductively coupled plasma reactive ion etch process for high aspect ratio etching of fused silica, borosilicate and aluminosilicate glass substrates",
abstract = "We report on the etching of glass substrates of various compositions in a modified inductively coupled plasma – reactive ion etch (ICP-RIE) tool using SF6 as the plasma source gas and NF3 and H2O gases introduced downstream near the surface of the wafer through a diffuser gas inlet. Using this modified system, we have been able to achieve etch rates as high as 1.06 μm/min, 1.04 μm/min, and 0.45 μm/min with surface smoothness of ∼2 {\AA}, ∼67 {\AA}, ∼4 {\AA} for fused silica, borosilicate glass, and aluminosilicate glass respectively after 5 min etches. We examine the role of ion flux and fluorine radicals and molecules on the etch rate and the etch smoothness. We analyze the results obtained on 41 etches through multivariate statistical analysis and use the Pearson coefficient and P-value to determine the importance of these parameters for each of the glass substrate compositions. Overall for all three glass compositions, etch rate is critically influenced by ion flux. Fluorine based radicals and molecular fragments influence both the etch rate and surface smoothness of fused silica whereas they primarily influence the surface smoothness for borosilicate glass. The large fraction of impurity atoms of Ca and Al in aluminosilicate glass form non-volatile fluorides in the etched areas and therefore the etch rate and surface smoothness of aluminosilicate glass is primarily influenced ion flux and very little by the fluorine chemistry. We also examine the role of the layout of the metal mask layer on how it influences the charging of glass substrates during etching and therefore the etch rate.",
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Modified inductively coupled plasma reactive ion etch process for high aspect ratio etching of fused silica, borosilicate and aluminosilicate glass substrates. / Zhang, Chenchen; Tadigadapa, Srinivas A.

In: Sensors and Actuators, A: Physical, Vol. 273, 15.04.2018, p. 147-158.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Tadigadapa, Srinivas A.

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AB - We report on the etching of glass substrates of various compositions in a modified inductively coupled plasma – reactive ion etch (ICP-RIE) tool using SF6 as the plasma source gas and NF3 and H2O gases introduced downstream near the surface of the wafer through a diffuser gas inlet. Using this modified system, we have been able to achieve etch rates as high as 1.06 μm/min, 1.04 μm/min, and 0.45 μm/min with surface smoothness of ∼2 Å, ∼67 Å, ∼4 Å for fused silica, borosilicate glass, and aluminosilicate glass respectively after 5 min etches. We examine the role of ion flux and fluorine radicals and molecules on the etch rate and the etch smoothness. We analyze the results obtained on 41 etches through multivariate statistical analysis and use the Pearson coefficient and P-value to determine the importance of these parameters for each of the glass substrate compositions. Overall for all three glass compositions, etch rate is critically influenced by ion flux. Fluorine based radicals and molecular fragments influence both the etch rate and surface smoothness of fused silica whereas they primarily influence the surface smoothness for borosilicate glass. The large fraction of impurity atoms of Ca and Al in aluminosilicate glass form non-volatile fluorides in the etched areas and therefore the etch rate and surface smoothness of aluminosilicate glass is primarily influenced ion flux and very little by the fluorine chemistry. We also examine the role of the layout of the metal mask layer on how it influences the charging of glass substrates during etching and therefore the etch rate.

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