New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles

Harry R. Allcock, Ursula Diefenbach, Shawn R. Pucher

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.

Original languageEnglish (US)
Pages (from-to)3091-3095
Number of pages5
JournalInorganic Chemistry
Volume33
Issue number14
DOIs
StatePublished - Jul 1 1994

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Nuclear magnetic resonance spectroscopy
Mass spectrometry
Nuclear magnetic resonance
nuclear magnetic resonance
Chemical analysis
mass spectroscopy
spectroscopy
triethylamine
1,2-cyclohexanediamine
1,2-benzenedithiol
1,2-diamino-4,5-dichlorobenzene
2,3-diaminonaphthalene
2,3-diaminopyridine
1,2-diaminobenzene

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

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title = "New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles",
abstract = "Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.",
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New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles. / Allcock, Harry R.; Diefenbach, Ursula; Pucher, Shawn R.

In: Inorganic Chemistry, Vol. 33, No. 14, 01.07.1994, p. 3091-3095.

Research output: Contribution to journalArticle

TY - JOUR

T1 - New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles

AU - Allcock, Harry R.

AU - Diefenbach, Ursula

AU - Pucher, Shawn R.

PY - 1994/7/1

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AB - Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.

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U2 - 10.1021/ic00092a013

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