New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles

Harry R. Allcock, Ursula Diefenbach, Shawn R. Pucher

Research output: Contribution to journalArticlepeer-review

53 Scopus citations

Abstract

Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.

Original languageEnglish (US)
Pages (from-to)3091-3095
Number of pages5
JournalInorganic Chemistry
Volume33
Issue number14
DOIs
StatePublished - Jul 1 1994

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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