NEW POLY(ORGANOPHOSPHAZENES) PREPARED BY POLYMERIZATION OF MONO-ALKYL AND 1,1-DIALKYL-CYCLOTRIPHOSPHAZENES, N3P3Cl5R AND 1,1-N3P3Cl4R2.

R. J. Ritchie, Harry R. Allcock

Research output: Contribution to journalConference article

1 Citation (Scopus)

Abstract

In the reported experimental program, a new class of high molecular weight polyphosphazenes, which contain direct-phosphorus-carbon bonds, has been prepared by the thermal polymerization of partially alkylated cyclic phosphazenes, N//3P//3Cl//5R, and 1,1-N//3P//3Cl//4R//2. Molecular structures of monomers used and polymers obtained are detailed. The discussion is summarized under headings - replacement of the residual chlorine in monomers; polymerization conditions; influence of alkyl groups on chain length; effects of the alkyl groups on general physical properties.

Original languageEnglish (US)
Pages (from-to)549-551
Number of pages3
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume20
Issue number2
StatePublished - Jan 1 1979
EventPap presented at a Meet, Spec Top in Poly Chem - Washington, DC, USA
Duration: Sep 10 1979Sep 14 1979

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Monomers
Polymerization
Chlorine
Chain length
Phosphorus
Molecular structure
Polymers
Carbon
Physical properties
Molecular weight
Hot Temperature

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

Cite this

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title = "NEW POLY(ORGANOPHOSPHAZENES) PREPARED BY POLYMERIZATION OF MONO-ALKYL AND 1,1-DIALKYL-CYCLOTRIPHOSPHAZENES, N3P3Cl5R AND 1,1-N3P3Cl4R2.",
abstract = "In the reported experimental program, a new class of high molecular weight polyphosphazenes, which contain direct-phosphorus-carbon bonds, has been prepared by the thermal polymerization of partially alkylated cyclic phosphazenes, N//3P//3Cl//5R, and 1,1-N//3P//3Cl//4R//2. Molecular structures of monomers used and polymers obtained are detailed. The discussion is summarized under headings - replacement of the residual chlorine in monomers; polymerization conditions; influence of alkyl groups on chain length; effects of the alkyl groups on general physical properties.",
author = "Ritchie, {R. J.} and Allcock, {Harry R.}",
year = "1979",
month = "1",
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pages = "549--551",
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TY - JOUR

T1 - NEW POLY(ORGANOPHOSPHAZENES) PREPARED BY POLYMERIZATION OF MONO-ALKYL AND 1,1-DIALKYL-CYCLOTRIPHOSPHAZENES, N3P3Cl5R AND 1,1-N3P3Cl4R2.

AU - Ritchie, R. J.

AU - Allcock, Harry R.

PY - 1979/1/1

Y1 - 1979/1/1

N2 - In the reported experimental program, a new class of high molecular weight polyphosphazenes, which contain direct-phosphorus-carbon bonds, has been prepared by the thermal polymerization of partially alkylated cyclic phosphazenes, N//3P//3Cl//5R, and 1,1-N//3P//3Cl//4R//2. Molecular structures of monomers used and polymers obtained are detailed. The discussion is summarized under headings - replacement of the residual chlorine in monomers; polymerization conditions; influence of alkyl groups on chain length; effects of the alkyl groups on general physical properties.

AB - In the reported experimental program, a new class of high molecular weight polyphosphazenes, which contain direct-phosphorus-carbon bonds, has been prepared by the thermal polymerization of partially alkylated cyclic phosphazenes, N//3P//3Cl//5R, and 1,1-N//3P//3Cl//4R//2. Molecular structures of monomers used and polymers obtained are detailed. The discussion is summarized under headings - replacement of the residual chlorine in monomers; polymerization conditions; influence of alkyl groups on chain length; effects of the alkyl groups on general physical properties.

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M3 - Conference article

AN - SCOPUS:0018520689

VL - 20

SP - 549

EP - 551

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

SN - 0032-3934

IS - 2

ER -