Abstract
In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.
| Original language | English (US) |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 64 |
| Issue number | 10 |
| DOIs | |
| State | Published - Oct 13 2008 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
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(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate. / Carter, Shawn M.; Xu, Nan; Khan, Masood A.; Powell, Douglas R.; Richter-Addo, George B.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 10, 13.10.2008.Research output: Contribution to journal › Article
TY - JOUR
T1 - (Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate
AU - Carter, Shawn M.
AU - Xu, Nan
AU - Khan, Masood A.
AU - Powell, Douglas R.
AU - Richter-Addo, George B.
PY - 2008/10/13
Y1 - 2008/10/13
N2 - In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.
AB - In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.
UR - http://www.scopus.com/inward/record.url?scp=53349153345&partnerID=8YFLogxK
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U2 - 10.1107/S1600536808030705
DO - 10.1107/S1600536808030705
M3 - Article
VL - 64
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 10
ER -