(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate

Shawn M. Carter, Nan Xu, Masood A. Khan, Douglas R. Powell, George B. Richter-Addo

Research output: Contribution to journalArticle

Abstract

In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number10
DOIs
StatePublished - Oct 13 2008

Fingerprint

Molybdenum
Benzene
molybdenum
Porphyrins
benzene
porphyrins
Atoms
Ions
Nitrates
Oxides
atoms
nitrates
ions
oxides
rings

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Carter, Shawn M. ; Xu, Nan ; Khan, Masood A. ; Powell, Douglas R. ; Richter-Addo, George B. / (Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate. In: Acta Crystallographica Section E: Structure Reports Online. 2008 ; Vol. 64, No. 10.
@article{b72f8856fab04cc19776c86679a595b7,
title = "(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate",
abstract = "In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) {\AA} towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.",
author = "Carter, {Shawn M.} and Nan Xu and Khan, {Masood A.} and Powell, {Douglas R.} and Richter-Addo, {George B.}",
year = "2008",
month = "10",
day = "13",
doi = "10.1107/S1600536808030705",
language = "English (US)",
volume = "64",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "10",

}

(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate. / Carter, Shawn M.; Xu, Nan; Khan, Masood A.; Powell, Douglas R.; Richter-Addo, George B.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 10, 13.10.2008.

Research output: Contribution to journalArticle

TY - JOUR

T1 - (Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate

AU - Carter, Shawn M.

AU - Xu, Nan

AU - Khan, Masood A.

AU - Powell, Douglas R.

AU - Richter-Addo, George B.

PY - 2008/10/13

Y1 - 2008/10/13

N2 - In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.

AB - In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.

UR - http://www.scopus.com/inward/record.url?scp=53349153345&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=53349153345&partnerID=8YFLogxK

U2 - 10.1107/S1600536808030705

DO - 10.1107/S1600536808030705

M3 - Article

VL - 64

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 10

ER -