In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.
|Original language||English (US)|
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|Publication status||Published - Oct 13 2008|
All Science Journal Classification (ASJC) codes
- Materials Science(all)
- Condensed Matter Physics