(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate

Shawn M. Carter, Nan Xu, Masood A. Khan, Douglas R. Powell, George B. Richter-Addo

Research output: Contribution to journalArticle

Abstract

In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.

Original languageEnglish (US)
Pages (from-to)m1337
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number10
DOIs
Publication statusPublished - Oct 13 2008

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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