Nonlinear phosphorescence quenching mechanism of gadolinium labeled porphyrin by oxygen on filter paper

Huimin Zhao, Lixin Zang, Feng Qin, Peng Wang, Hua Zhao, Zhiguo Zhang, Wenwu Cao

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Nonlinear phosphorescence quenching mechanism of gadolinium labeled hematoporphyrin monomethyl ether (Gd-HMME) by oxygen on the filter paper was studied. The intensity Stern-Volmer plot was found to be approximately linear for oxygen concentration from 10% to 100%, but showing a negative curvature from 0% to 10%. The lifetime plot has similar changing trend. The intensity plot is slightly higher than the lifetime plot reflecting the existence of static quenching. The nonlinear responses were related to the nonlinear solubility of oxygen, which perfectly satisfy the nonlinear solubility model. Data analysis indicates that the static quenching rate constant is unchanged and the percentage of static quenching is about 35% ± 3% in the whole range of oxygen concentration.

Original languageEnglish (US)
Pages (from-to)7-11
Number of pages5
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume316
DOIs
StatePublished - Feb 1 2016

Fingerprint

Phosphorescence
Gadolinium
Porphyrins
phosphorescence
gadolinium
porphyrins
Quenching
plots
quenching
Oxygen
filters
oxygen
solubility
Solubility
life (durability)
Ethers
ethers
Rate constants
curvature
trends

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Physics and Astronomy(all)

Cite this

Zhao, Huimin ; Zang, Lixin ; Qin, Feng ; Wang, Peng ; Zhao, Hua ; Zhang, Zhiguo ; Cao, Wenwu. / Nonlinear phosphorescence quenching mechanism of gadolinium labeled porphyrin by oxygen on filter paper. In: Journal of Photochemistry and Photobiology A: Chemistry. 2016 ; Vol. 316. pp. 7-11.
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abstract = "Nonlinear phosphorescence quenching mechanism of gadolinium labeled hematoporphyrin monomethyl ether (Gd-HMME) by oxygen on the filter paper was studied. The intensity Stern-Volmer plot was found to be approximately linear for oxygen concentration from 10{\%} to 100{\%}, but showing a negative curvature from 0{\%} to 10{\%}. The lifetime plot has similar changing trend. The intensity plot is slightly higher than the lifetime plot reflecting the existence of static quenching. The nonlinear responses were related to the nonlinear solubility of oxygen, which perfectly satisfy the nonlinear solubility model. Data analysis indicates that the static quenching rate constant is unchanged and the percentage of static quenching is about 35{\%} ± 3{\%} in the whole range of oxygen concentration.",
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Nonlinear phosphorescence quenching mechanism of gadolinium labeled porphyrin by oxygen on filter paper. / Zhao, Huimin; Zang, Lixin; Qin, Feng; Wang, Peng; Zhao, Hua; Zhang, Zhiguo; Cao, Wenwu.

In: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 316, 01.02.2016, p. 7-11.

Research output: Contribution to journalArticle

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AU - Zhao, Huimin

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AU - Qin, Feng

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AU - Zhang, Zhiguo

AU - Cao, Wenwu

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AB - Nonlinear phosphorescence quenching mechanism of gadolinium labeled hematoporphyrin monomethyl ether (Gd-HMME) by oxygen on the filter paper was studied. The intensity Stern-Volmer plot was found to be approximately linear for oxygen concentration from 10% to 100%, but showing a negative curvature from 0% to 10%. The lifetime plot has similar changing trend. The intensity plot is slightly higher than the lifetime plot reflecting the existence of static quenching. The nonlinear responses were related to the nonlinear solubility of oxygen, which perfectly satisfy the nonlinear solubility model. Data analysis indicates that the static quenching rate constant is unchanged and the percentage of static quenching is about 35% ± 3% in the whole range of oxygen concentration.

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