Novel aluminum-based, transition metal-free, catalytic systems for homo and copolymerization of alkenes

Jang Sub Kim, Ayusman Sen

Research output: Contribution to journalConference article

Abstract

A study was carried out to demonstrate that simple alkylaluminum compounds, when activated by suitable Lewis acids, can catalyze the homo and copolymerization of ethene and propene to high molecular weight polymers with narrow polydispersities. The obtained compounds were characterized by 1H and 13C-NMR spectroscopy.

Original languageEnglish (US)
Pages (from-to)1891-1892
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume41
Issue number2
StatePublished - Aug 1 2000
EventWashington,DC. Meeting - Washington, DC, USA
Duration: Aug 20 2000Aug 24 2000

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Lewis Acids
Polydispersity
Alkenes
Aluminum
Copolymerization
Nuclear magnetic resonance spectroscopy
Olefins
Propylene
Transition metals
Polymers
Molecular weight
Acids
ethylene
propylene

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

Cite this

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abstract = "A study was carried out to demonstrate that simple alkylaluminum compounds, when activated by suitable Lewis acids, can catalyze the homo and copolymerization of ethene and propene to high molecular weight polymers with narrow polydispersities. The obtained compounds were characterized by 1H and 13C-NMR spectroscopy.",
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AU - Sen, Ayusman

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AB - A study was carried out to demonstrate that simple alkylaluminum compounds, when activated by suitable Lewis acids, can catalyze the homo and copolymerization of ethene and propene to high molecular weight polymers with narrow polydispersities. The obtained compounds were characterized by 1H and 13C-NMR spectroscopy.

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JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

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