Nucleation of epitaxial graphene on SiC(0001)

Joshua Alexander Robinson, Xiaojun Weng, Kathleen Trumbull, Randall Cavalero, Maxwell Wetherington, Eric Frantz, Michael LaBella, Zachary Hughes, Mark Andrew Fanton, David W. Snyder

Research output: Contribution to journalArticle

117 Citations (Scopus)

Abstract

A promising route for the synthesis of large-area graphene, suitable for standard device fabrication techniques, is the sublimation of silicon from silicon carbide at elevated temperatures (>1200 °C). Previous reports suggest that graphene nucleates along the (110n) plane, known as terrace step edges, on the silicon carbide surface. However, to date, a fundamental understanding of the nucleation of graphene on silicon carbide is lacking. We provide the first direct evidence that nucleation of epitaxial graphene on silicon carbide occurs along the (110n) plane and show that the nucleated graphene quality improves as the synthesis temperature is increased. Additionally, we find that graphene on the (110n) plane can be significantly thicker than its (0001) counterpart and appears not to have a thickness limit. Finally, we find that graphene along the (110n) plane can contain a high density of structural defects, often the result of the underlying substrate, which will undoubtedly degrade the electronic properties of the material. Addressing the presence of non-uniform graphene that may contain structural defects at terrace step edges will be key to the development of a large-scale graphene technology derived from silicon carbide.

Original languageEnglish (US)
Pages (from-to)153-158
Number of pages6
JournalACS Nano
Volume4
Issue number1
DOIs
StatePublished - Jan 26 2010

Fingerprint

Graphite
Graphene
graphene
Nucleation
nucleation
Silicon carbide
silicon carbides
Defects
Sublimation
defects
Silicon
synthesis
sublimation
Electronic properties
routes
silicon carbide
Fabrication
Temperature
fabrication
temperature

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Robinson, J. A., Weng, X., Trumbull, K., Cavalero, R., Wetherington, M., Frantz, E., ... Snyder, D. W. (2010). Nucleation of epitaxial graphene on SiC(0001). ACS Nano, 4(1), 153-158. https://doi.org/10.1021/nn901248j
Robinson, Joshua Alexander ; Weng, Xiaojun ; Trumbull, Kathleen ; Cavalero, Randall ; Wetherington, Maxwell ; Frantz, Eric ; LaBella, Michael ; Hughes, Zachary ; Fanton, Mark Andrew ; Snyder, David W. / Nucleation of epitaxial graphene on SiC(0001). In: ACS Nano. 2010 ; Vol. 4, No. 1. pp. 153-158.
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Robinson, JA, Weng, X, Trumbull, K, Cavalero, R, Wetherington, M, Frantz, E, LaBella, M, Hughes, Z, Fanton, MA & Snyder, DW 2010, 'Nucleation of epitaxial graphene on SiC(0001)', ACS Nano, vol. 4, no. 1, pp. 153-158. https://doi.org/10.1021/nn901248j

Nucleation of epitaxial graphene on SiC(0001). / Robinson, Joshua Alexander; Weng, Xiaojun; Trumbull, Kathleen; Cavalero, Randall; Wetherington, Maxwell; Frantz, Eric; LaBella, Michael; Hughes, Zachary; Fanton, Mark Andrew; Snyder, David W.

In: ACS Nano, Vol. 4, No. 1, 26.01.2010, p. 153-158.

Research output: Contribution to journalArticle

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Robinson JA, Weng X, Trumbull K, Cavalero R, Wetherington M, Frantz E et al. Nucleation of epitaxial graphene on SiC(0001). ACS Nano. 2010 Jan 26;4(1):153-158. https://doi.org/10.1021/nn901248j