O-bridged medium sized rings via bicyclic oxonium ylides

F. G. West, Thomas Eberlein, Richland W. Tester

Research output: Contribution to journalArticle

59 Citations (Scopus)

Abstract

Fused bicyclic oxonium ylides, generated with catalytic Rh 2(OAc)4 from cyclic ethers bearing pendant diazo ketones, undergo a [1,2]- or [2,3]-shift to give O-bridged seven- or eight-membered carbocycles, in several cases with a high degree of stereoselectivity.

Original languageEnglish (US)
Pages (from-to)2857-2859
Number of pages3
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number23
StatePublished - Dec 1 1993

Fingerprint

Bearings (structural)
Cyclic Ethers
Stereoselectivity
Ketones
hydronium ion

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

West, F. G. ; Eberlein, Thomas ; Tester, Richland W. / O-bridged medium sized rings via bicyclic oxonium ylides. In: Journal of the Chemical Society, Perkin Transactions 1. 1993 ; No. 23. pp. 2857-2859.
@article{f0726208b2424823930919c5f9e74c86,
title = "O-bridged medium sized rings via bicyclic oxonium ylides",
abstract = "Fused bicyclic oxonium ylides, generated with catalytic Rh 2(OAc)4 from cyclic ethers bearing pendant diazo ketones, undergo a [1,2]- or [2,3]-shift to give O-bridged seven- or eight-membered carbocycles, in several cases with a high degree of stereoselectivity.",
author = "West, {F. G.} and Thomas Eberlein and Tester, {Richland W.}",
year = "1993",
month = "12",
day = "1",
language = "English (US)",
pages = "2857--2859",
journal = "Journal of the Chemical Society, Perkin Transactions 1",
issn = "1472-7781",
publisher = "Chemical Society",
number = "23",

}

O-bridged medium sized rings via bicyclic oxonium ylides. / West, F. G.; Eberlein, Thomas; Tester, Richland W.

In: Journal of the Chemical Society, Perkin Transactions 1, No. 23, 01.12.1993, p. 2857-2859.

Research output: Contribution to journalArticle

TY - JOUR

T1 - O-bridged medium sized rings via bicyclic oxonium ylides

AU - West, F. G.

AU - Eberlein, Thomas

AU - Tester, Richland W.

PY - 1993/12/1

Y1 - 1993/12/1

N2 - Fused bicyclic oxonium ylides, generated with catalytic Rh 2(OAc)4 from cyclic ethers bearing pendant diazo ketones, undergo a [1,2]- or [2,3]-shift to give O-bridged seven- or eight-membered carbocycles, in several cases with a high degree of stereoselectivity.

AB - Fused bicyclic oxonium ylides, generated with catalytic Rh 2(OAc)4 from cyclic ethers bearing pendant diazo ketones, undergo a [1,2]- or [2,3]-shift to give O-bridged seven- or eight-membered carbocycles, in several cases with a high degree of stereoselectivity.

UR - http://www.scopus.com/inward/record.url?scp=37049075893&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049075893&partnerID=8YFLogxK

M3 - Article

SP - 2857

EP - 2859

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

SN - 1472-7781

IS - 23

ER -