Observations of bromine monoxide transport in the Arctic sustained on aerosol particles

Peter K. Peterson, Denis Pöhler, Holger Sihler, Johannes Zielcke, Stephan General, Udo Frieß, Ulrich Platt, William R. Simpson, Son V. Nghiem, Paul B. Shepson, Brian H. Stirm, Suresh Dhaniyala, Thomas Wagner, Dana R. Caulton, Jose D. Fuentes, Kerri A. Pratt

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The return of sunlight in the polar spring leads to the production of reactive halogen species from the surface snowpack, significantly altering the chemical composition of the Arctic near-surface atmosphere and the fate of long-range transported pollutants, including mercury. Recent work has shown the initial production of reactive bromine at the Arctic surface snowpack; however, we have limited knowledge of the vertical extent of this chemistry, as well as the lifetime and possible transport of reactive bromine aloft. Here, we present bromine monoxide (BrO) and aerosol particle measurements obtained during the March 2012 BRomine Ozone Mercury EXperiment (BROMEX) near Utqia?vik (Barrow), AK. The airborne differential optical absorption spectroscopy (DOAS) measurements provided an unprecedented level of spatial resolution, over 2 orders of magnitude greater than satellite observations and with vertical resolution unable to be achieved by satellite methods, for BrO in the Arctic. This novel method provided quantitative identification of a BrO plume, between 500ĝ€m and 1ĝ€km aloft, moving at the speed of the air mass. Concurrent aerosol particle measurements suggest that this lofted reactive bromine plume was transported and maintained at elevated levels through heterogeneous reactions on colocated supermicron aerosol particles, independent of surface snowpack bromine chemistry. This chemical transport mechanism explains the large spatial extents often observed for reactive bromine chemistry, which impacts atmospheric composition and pollutant fate across the Arctic region, beyond areas of initial snowpack halogen production. The possibility of BrO enhancements disconnected from the surface potentially contributes to sustaining BrO in the free troposphere and must also be considered in the interpretation of satellite BrO column observations, particularly in the context of the rapidly changing Arctic sea ice and snowpack.

Original languageEnglish (US)
Pages (from-to)7567-7579
Number of pages13
JournalAtmospheric Chemistry and Physics
Volume17
Issue number12
DOIs
StatePublished - Jun 22 2017

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bromine
aerosol
snowpack
halogen
plume
atomic absorption spectroscopy
air mass
sea ice
troposphere
spatial resolution
atmospheric pollution
chemical composition
ozone

All Science Journal Classification (ASJC) codes

  • Atmospheric Science

Cite this

Peterson, P. K., Pöhler, D., Sihler, H., Zielcke, J., General, S., Frieß, U., ... Pratt, K. A. (2017). Observations of bromine monoxide transport in the Arctic sustained on aerosol particles. Atmospheric Chemistry and Physics, 17(12), 7567-7579. https://doi.org/10.5194/acp-17-7567-2017
Peterson, Peter K. ; Pöhler, Denis ; Sihler, Holger ; Zielcke, Johannes ; General, Stephan ; Frieß, Udo ; Platt, Ulrich ; Simpson, William R. ; Nghiem, Son V. ; Shepson, Paul B. ; Stirm, Brian H. ; Dhaniyala, Suresh ; Wagner, Thomas ; Caulton, Dana R. ; Fuentes, Jose D. ; Pratt, Kerri A. / Observations of bromine monoxide transport in the Arctic sustained on aerosol particles. In: Atmospheric Chemistry and Physics. 2017 ; Vol. 17, No. 12. pp. 7567-7579.
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Peterson, PK, Pöhler, D, Sihler, H, Zielcke, J, General, S, Frieß, U, Platt, U, Simpson, WR, Nghiem, SV, Shepson, PB, Stirm, BH, Dhaniyala, S, Wagner, T, Caulton, DR, Fuentes, JD & Pratt, KA 2017, 'Observations of bromine monoxide transport in the Arctic sustained on aerosol particles', Atmospheric Chemistry and Physics, vol. 17, no. 12, pp. 7567-7579. https://doi.org/10.5194/acp-17-7567-2017

Observations of bromine monoxide transport in the Arctic sustained on aerosol particles. / Peterson, Peter K.; Pöhler, Denis; Sihler, Holger; Zielcke, Johannes; General, Stephan; Frieß, Udo; Platt, Ulrich; Simpson, William R.; Nghiem, Son V.; Shepson, Paul B.; Stirm, Brian H.; Dhaniyala, Suresh; Wagner, Thomas; Caulton, Dana R.; Fuentes, Jose D.; Pratt, Kerri A.

In: Atmospheric Chemistry and Physics, Vol. 17, No. 12, 22.06.2017, p. 7567-7579.

Research output: Contribution to journalArticle

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T1 - Observations of bromine monoxide transport in the Arctic sustained on aerosol particles

AU - Peterson, Peter K.

AU - Pöhler, Denis

AU - Sihler, Holger

AU - Zielcke, Johannes

AU - General, Stephan

AU - Frieß, Udo

AU - Platt, Ulrich

AU - Simpson, William R.

AU - Nghiem, Son V.

AU - Shepson, Paul B.

AU - Stirm, Brian H.

AU - Dhaniyala, Suresh

AU - Wagner, Thomas

AU - Caulton, Dana R.

AU - Fuentes, Jose D.

AU - Pratt, Kerri A.

PY - 2017/6/22

Y1 - 2017/6/22

N2 - The return of sunlight in the polar spring leads to the production of reactive halogen species from the surface snowpack, significantly altering the chemical composition of the Arctic near-surface atmosphere and the fate of long-range transported pollutants, including mercury. Recent work has shown the initial production of reactive bromine at the Arctic surface snowpack; however, we have limited knowledge of the vertical extent of this chemistry, as well as the lifetime and possible transport of reactive bromine aloft. Here, we present bromine monoxide (BrO) and aerosol particle measurements obtained during the March 2012 BRomine Ozone Mercury EXperiment (BROMEX) near Utqia?vik (Barrow), AK. The airborne differential optical absorption spectroscopy (DOAS) measurements provided an unprecedented level of spatial resolution, over 2 orders of magnitude greater than satellite observations and with vertical resolution unable to be achieved by satellite methods, for BrO in the Arctic. This novel method provided quantitative identification of a BrO plume, between 500ĝ€m and 1ĝ€km aloft, moving at the speed of the air mass. Concurrent aerosol particle measurements suggest that this lofted reactive bromine plume was transported and maintained at elevated levels through heterogeneous reactions on colocated supermicron aerosol particles, independent of surface snowpack bromine chemistry. This chemical transport mechanism explains the large spatial extents often observed for reactive bromine chemistry, which impacts atmospheric composition and pollutant fate across the Arctic region, beyond areas of initial snowpack halogen production. The possibility of BrO enhancements disconnected from the surface potentially contributes to sustaining BrO in the free troposphere and must also be considered in the interpretation of satellite BrO column observations, particularly in the context of the rapidly changing Arctic sea ice and snowpack.

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