OH and HO2 measurements using laser-induced fluorescence

James H. Mather, Philip S. Stevens, William Henry Brune

Research output: Contribution to journalArticle

67 Citations (Scopus)

Abstract

During August and September 1993 a laser-induced fluorescence (LIF) instrument was used to observe OH and HO2 as part of the Tropospheric OH Photochemistry Experiment (TOHPE) in the mountains west of Boulder, Colorado. A prototype version of this instrument has been described previously. Modifications were made to the instrument for TOHPE, including the integration of a new dye laser. The instrument was calibrated by producing known amounts of OH and HO2 above the instrument inlet. HO2 was measured on 19 days during TOHPE, while OH was measured on 5 days. Although poor laser performance limited the detection limit to 1 to 2×106 cm-3 for an integration time of 300 s and a signal-to-noise ratio of 1, OH concentrations were observed to reach 3 to 7×106 cm-3 near midday. HO2 typically peaked near 1×108 cm-3. HO2 consistently reached its maximum near local noon. Observations made with the LIF instrument are compared with observations made with an ion-assisted technique.

Original languageEnglish (US)
Pages (from-to)6427-6436
Number of pages10
JournalJournal of Geophysical Research
Volume102
Issue number5
StatePublished - Mar 20 1997

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laser induced fluorescence
photochemistry
lasers
Fluorescence
fluorescence
Lasers
Photochemical reactions
laser
photochemical reactions
experiment
boulder
signal-to-noise ratio
dye
prototypes
dyes
detection limit
noon
mountain
Dye lasers
ion

All Science Journal Classification (ASJC) codes

  • Geophysics
  • Oceanography
  • Forestry
  • Ecology
  • Aquatic Science
  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth-Surface Processes
  • Atmospheric Science
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science
  • Palaeontology

Cite this

Mather, James H. ; Stevens, Philip S. ; Brune, William Henry. / OH and HO2 measurements using laser-induced fluorescence. In: Journal of Geophysical Research. 1997 ; Vol. 102, No. 5. pp. 6427-6436.
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Mather, JH, Stevens, PS & Brune, WH 1997, 'OH and HO2 measurements using laser-induced fluorescence', Journal of Geophysical Research, vol. 102, no. 5, pp. 6427-6436.

OH and HO2 measurements using laser-induced fluorescence. / Mather, James H.; Stevens, Philip S.; Brune, William Henry.

In: Journal of Geophysical Research, Vol. 102, No. 5, 20.03.1997, p. 6427-6436.

Research output: Contribution to journalArticle

TY - JOUR

T1 - OH and HO2 measurements using laser-induced fluorescence

AU - Mather, James H.

AU - Stevens, Philip S.

AU - Brune, William Henry

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N2 - During August and September 1993 a laser-induced fluorescence (LIF) instrument was used to observe OH and HO2 as part of the Tropospheric OH Photochemistry Experiment (TOHPE) in the mountains west of Boulder, Colorado. A prototype version of this instrument has been described previously. Modifications were made to the instrument for TOHPE, including the integration of a new dye laser. The instrument was calibrated by producing known amounts of OH and HO2 above the instrument inlet. HO2 was measured on 19 days during TOHPE, while OH was measured on 5 days. Although poor laser performance limited the detection limit to 1 to 2×106 cm-3 for an integration time of 300 s and a signal-to-noise ratio of 1, OH concentrations were observed to reach 3 to 7×106 cm-3 near midday. HO2 typically peaked near 1×108 cm-3. HO2 consistently reached its maximum near local noon. Observations made with the LIF instrument are compared with observations made with an ion-assisted technique.

AB - During August and September 1993 a laser-induced fluorescence (LIF) instrument was used to observe OH and HO2 as part of the Tropospheric OH Photochemistry Experiment (TOHPE) in the mountains west of Boulder, Colorado. A prototype version of this instrument has been described previously. Modifications were made to the instrument for TOHPE, including the integration of a new dye laser. The instrument was calibrated by producing known amounts of OH and HO2 above the instrument inlet. HO2 was measured on 19 days during TOHPE, while OH was measured on 5 days. Although poor laser performance limited the detection limit to 1 to 2×106 cm-3 for an integration time of 300 s and a signal-to-noise ratio of 1, OH concentrations were observed to reach 3 to 7×106 cm-3 near midday. HO2 typically peaked near 1×108 cm-3. HO2 consistently reached its maximum near local noon. Observations made with the LIF instrument are compared with observations made with an ion-assisted technique.

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