Oil sorption by exfoliated graphite from dilute oil-water emulsion for practical applications in produced water treatments

Kenji Takeuchi, Masatsugu Fujishige, Hidenori Kitazawa, Noboru Akuzawa, Josue Ortiz Medina, Aaron Morelos-Gomez, Rodolfo Cruz-Silva, Takumi Araki, Takuya Hayashi, Mauricio Terrones, Morinobu Endo

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13 Scopus citations

Abstract

We used engine oil-water emulsion as a model produced water to evaluate the oil sorption properties of exfoliated graphite (EG) and showed that 100mg/L of oil in emulsion can be reduced to a concentration of a 0.1-few mg/L using as-received commercially available EG and surface modified EG subjected to an additional oxidation treatment. Oil at a concentration of less than 15mg/L, the standard of typical water treatment processes. Although EG also sorbs water, it sorbs oil preferentially and the oil concentration of the sorbed phase in EG was estimated to be about 200 times that of the initial untreated emulsion. The sorption mechanism was discussed with the aid of the ab-initio relaxation calculation and classical molecular dynamics (MD) simulation for n-Hexane (C6H14) adsorption on graphene. When EG was incorporated with micron-size iron particles, the oil sorbed EG was found to be effectively recovered from emulsion by using magnetic field. The oil concentration in emulsion treated with EG was able to reduce down to the level comparable to that achieved by nanofiltration (NF) or reverse osmosis (RO) membrane treatment. We concluded that EG from natural graphite can effectively remove oil component during the treatment of emulsion and exhibits high potential for practical use.

Original languageEnglish (US)
Pages (from-to)91-98
Number of pages8
JournalJournal of Water Process Engineering
Volume8
DOIs
StatePublished - Dec 1 2015

All Science Journal Classification (ASJC) codes

  • Biotechnology
  • Safety, Risk, Reliability and Quality
  • Waste Management and Disposal
  • Process Chemistry and Technology

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    Takeuchi, K., Fujishige, M., Kitazawa, H., Akuzawa, N., Medina, J. O., Morelos-Gomez, A., Cruz-Silva, R., Araki, T., Hayashi, T., Terrones, M., & Endo, M. (2015). Oil sorption by exfoliated graphite from dilute oil-water emulsion for practical applications in produced water treatments. Journal of Water Process Engineering, 8, 91-98. https://doi.org/10.1016/j.jwpe.2015.09.002