Ollgomerizatlon and Isomerlzatlon of Olefins by η3-Allyl Complexes of Palladium. The Role of the Allyl Group

Ayusman Sen; Ta Wang Lai

doi:10.1021/om50002a027

Ollgomerizatlon and Isomerlzatlon of Olefins by η3-Allyl Complexes of Palladium. The Role of the Allyl Group

Ayusman Sen, Ta Wang Lai

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

[(η³-C₃H₅)Pd(CD₃NO₂)₂](BF₄) is a catalyst for the dimerization and the isomerization of olefins. The allyl group is retained in the course of these catalytic reactions. A carbonium ion mechanism which does not involve the participation of the allyl group is proposed.

Original language	English (US)
Pages (from-to)	1059-1060
Number of pages	2
Journal	Organometallics
Volume	2
Issue number	8
DOIs	https://doi.org/10.1021/om50002a027
State	Published - Aug 1983

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om50002a027

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title = "Ollgomerizatlon and Isomerlzatlon of Olefins by η3-Allyl Complexes of Palladium. The Role of the Allyl Group",

abstract = "[(η3-C3H5)Pd(CD3NO2)2](BF4) is a catalyst for the dimerization and the isomerization of olefins. The allyl group is retained in the course of these catalytic reactions. A carbonium ion mechanism which does not involve the participation of the allyl group is proposed.",

author = "Ayusman Sen and Lai, {Ta Wang}",

year = "1983",

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AB - [(η3-C3H5)Pd(CD3NO2)2](BF4) is a catalyst for the dimerization and the isomerization of olefins. The allyl group is retained in the course of these catalytic reactions. A carbonium ion mechanism which does not involve the participation of the allyl group is proposed.

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