On a novel self-regulating shape memory polymer composite

Fei Gao, Seyul Son, Kyungmook Park, David Biggs, Courtney Andrews, Eric M. Mockensturm, Nakhiah C. Goulbourne

Research output: Chapter in Book/Report/Conference proceedingConference contribution

3 Scopus citations

Abstract

Polyurethane shape memory polymers (PU-SMPs) are active materials that can be transformed into complex shapes with the ability to recover their original shape even after undergoing large deformations [1]. Because of their light weight, large recoverability, low cost, and high compliance, SMPs can be potentially employed as actuators, MEMS devices, temperature sensors, and damping elements to name a few [2-3]. One of the key challenges in implementing SMPs is the response time which is limited by the method of heating and cooling and the material. Unlike shape memory alloys, SMPs can be activated by multiple stimuli including lasers, resistive heating, electric fields, and magnetic fields [4]. While these methods may provide an efficient way of heating the SMP, they rely on the slow process of passive conduction for cooling. In this paper, a self regulating SMP (SR-SMP) composite is introduced, whereby a novel heating and cooling system consisting of embedded silica capillary tubes in the SMP (DiAPLEX® MP4510: SMP Technologies, Inc.) has been developed. The tubes are used to pump hot/cold fluid through the SMP membrane and hence provide a local temperature source. In order to show the effectiveness and efficiency of the mechanism, the thermomechanical response of the SR-SMP is compared experimentally to a SMP with "conventional" i.e. global heating and cooling mechanisms. It is shown that the SR-SMP has a faster thermomechanical response. It has been demonstrated previously that soft SMPs can be controlled by an electric field while in the rubbery phase, thus taking advantage of the Maxwell stress or electrostatic stress effect. Thermomechanical characterization of PU-SMPs is described for different weight percentages of resin (Diphenylmethane-4, 4′-diisocyanate) and hardener (1,4-Butanediol). Varying the percent hardener reduced the effective cross-link density of the polymer and hence the thermomechanical properties. The electromechanical response of pure SMP and SR-SMP is predicted numerically. The numerical computation indicates that the softer SMPs (resin:hardener = 5:4, 8:7, and 9:8) could be used as electroactive polymers.

Original languageEnglish (US)
Title of host publicationBehavior and Mechanics of Multifunctional Materials and Composites 2011
DOIs
StatePublished - Jun 6 2011
EventBehavior and Mechanics of Multifunctional Materials and Composites 2011 - San Diego, CA, United States
Duration: Mar 7 2011Mar 9 2011

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume7978
ISSN (Print)0277-786X

Other

OtherBehavior and Mechanics of Multifunctional Materials and Composites 2011
CountryUnited States
CitySan Diego, CA
Period3/7/113/9/11

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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  • Cite this

    Gao, F., Son, S., Park, K., Biggs, D., Andrews, C., Mockensturm, E. M., & Goulbourne, N. C. (2011). On a novel self-regulating shape memory polymer composite. In Behavior and Mechanics of Multifunctional Materials and Composites 2011 [797816] (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 7978). https://doi.org/10.1117/12.881930