On the embrittlement of zircaloy-4 under RIA-relevant conditions

R. S. Daum, S. Majumdar, D. W. Bates, Arthur Thompson Motta, D. A. Koss, M. C. Billone

Research output: Contribution to journalConference article

30 Scopus citations

Abstract

The extended use of Zircaloy cladding in light water reactors degrades its mechanical properties by a combination of irradiation embrittlement, coolant-side oxidation, hydrogen pickup, and hydride formation. The hydrides are usually concentrated in the form of a dense layer or rim near the cooler outer surface of the cladding, Utilizing plane-strain ring-stretch tests to approximate the loading path in a reactivity-initiated accident (RIA) transient, we examined the influence of a hydride rim on the fracture behavior of unirradiated Zircaloy-4 cladding at room temperature and 300°C. Failure is sensitive to hydride-rim thickness such that cladding tubes with a hydride-rim thickness > 100 μm (≈700 wppm total hydrogen) exhibit brittle behavior, while those with a thickness <90 μm (≈600 wppm) remain ductile. The mechanism of failure is identified as strain-induced crack initiation within the hydride rim and failure within the uncracked ligament due to either a shear instability or damage-induced fracture. We also report some preliminary results of the uniaxial tensile behavior of low-Sn Zircaloy-4 cladding tubes in a cold-worked, stress-relieved condition in the transverse (hoop) direction at strain rates of 0.001/s and 0.2/s and temperatures of 26 to 400°.

Original languageEnglish (US)
Pages (from-to)702-718
Number of pages17
JournalASTM Special Technical Publication
Issue number1423
StatePublished - Jan 1 2002
EventZirconium in the Nuclear Industry: Thirteenth International Symposium - Annecy, France
Duration: Jun 10 2001Oct 14 2001

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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    Daum, R. S., Majumdar, S., Bates, D. W., Motta, A. T., Koss, D. A., & Billone, M. C. (2002). On the embrittlement of zircaloy-4 under RIA-relevant conditions. ASTM Special Technical Publication, (1423), 702-718.