On the removal of hexavalent chromium from a Class F fly ash

F. E. Huggins, M. Rezaee, R. Q. Honaker, J. C. Hower

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Coarse and fine samples of a Class F fly ash obtained from commercial combustion of Illinois bituminous coal have been exposed to two long-term leaching tests designed to simulate conditions in waste impoundments. ICP-AES analysis indicated that the coarse and fine fly ash samples contained 135 and 171 mg/kg Cr, respectively. Measurements by XAFS spectroscopy showed that the ash samples originally contained 5 and 8% of the chromium, respectively, in the hexavalent oxidation state, Cr(VI). After exposure to water for more than four months, the percentage of chromium as Cr(VI) in the fly-ash decreased significantly for the coarse and fine fly-ash in both tests. Combining the XAFS data with ICP-AES data on the concentration of chromium in the leachates indicated that, after the nineteen-week-long, more aggressive, kinetic test on the coarse fly ash, approximately 60% of the Cr(VI) had been leached, 20% had been reduced to Cr(III) and retained in the ash, and 20% remained as Cr(VI) in the ash.In contrast, during the six-month-long baseline test, very little Cr was actually leached from either the coarse or the fine fly-ash (<0.1 mg/kg); rather, about 66% and 20%, respectively, of the original Cr(VI) in the coarse and fine fly-ash was retained in the ash in that form, while the remainder, 34% and 80%, respectively, was reduced and retained in the ash as Cr(III). The results are interpreted as indicating that Cr(VI) present in Class F fly-ash can be reduced to Cr(III) when in contact with water and that such chemical reduction can compete with physical removal of Cr(VI) from the ash by aqueous leaching.

Original languageEnglish (US)
Pages (from-to)105-110
Number of pages6
JournalWaste Management
Volume51
DOIs
StatePublished - May 1 2016

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fly ash
chromium
ash
leaching
bituminous coal
removal
impoundment
leachate
combustion
spectroscopy
oxidation
kinetics
water
test

All Science Journal Classification (ASJC) codes

  • Waste Management and Disposal

Cite this

Huggins, F. E. ; Rezaee, M. ; Honaker, R. Q. ; Hower, J. C. / On the removal of hexavalent chromium from a Class F fly ash. In: Waste Management. 2016 ; Vol. 51. pp. 105-110.
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On the removal of hexavalent chromium from a Class F fly ash. / Huggins, F. E.; Rezaee, M.; Honaker, R. Q.; Hower, J. C.

In: Waste Management, Vol. 51, 01.05.2016, p. 105-110.

Research output: Contribution to journalArticle

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AU - Rezaee, M.

AU - Honaker, R. Q.

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AB - Coarse and fine samples of a Class F fly ash obtained from commercial combustion of Illinois bituminous coal have been exposed to two long-term leaching tests designed to simulate conditions in waste impoundments. ICP-AES analysis indicated that the coarse and fine fly ash samples contained 135 and 171 mg/kg Cr, respectively. Measurements by XAFS spectroscopy showed that the ash samples originally contained 5 and 8% of the chromium, respectively, in the hexavalent oxidation state, Cr(VI). After exposure to water for more than four months, the percentage of chromium as Cr(VI) in the fly-ash decreased significantly for the coarse and fine fly-ash in both tests. Combining the XAFS data with ICP-AES data on the concentration of chromium in the leachates indicated that, after the nineteen-week-long, more aggressive, kinetic test on the coarse fly ash, approximately 60% of the Cr(VI) had been leached, 20% had been reduced to Cr(III) and retained in the ash, and 20% remained as Cr(VI) in the ash.In contrast, during the six-month-long baseline test, very little Cr was actually leached from either the coarse or the fine fly-ash (<0.1 mg/kg); rather, about 66% and 20%, respectively, of the original Cr(VI) in the coarse and fine fly-ash was retained in the ash in that form, while the remainder, 34% and 80%, respectively, was reduced and retained in the ash as Cr(III). The results are interpreted as indicating that Cr(VI) present in Class F fly-ash can be reduced to Cr(III) when in contact with water and that such chemical reduction can compete with physical removal of Cr(VI) from the ash by aqueous leaching.

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