Optical properties of a melt-quenched metal–organic framework glass

Ang Qiao, Haizheng Tao, Michael P. Carson, Scott W. Aldrich, Lynn M. Thirion, Thomas D. Bennett, John C. Mauro, Yuanzheng Yue

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Abstract

Metal–organic framework (MOF) glasses are characterized by the possession of both inorganic and organic components, linked in a continuous network structure by coordination bonds. To the best of our knowledge, the optical properties of MOF glasses have not been reported until now. In this work, we prepared a transparent bubble-free bulk MOF glass, namely, the ZIF-62 glass (ZnIm 2−x bIm x ), using our newly developed hot-pressing technique, and measured its optical properties. The ZIF-62 glass has a high transmittance (up to 90%) in the visible and near-infrared wavelength ranges, which is comparable to that of many oxide glasses. Using the Becke line n D method, we found that the ZIF-62 glass exhibits a refractive index (1.56) similar to most inorganic glasses, though a lower Abbe number (∼31).

Original languageEnglish (US)
Pages (from-to)1623-1625
Number of pages3
JournalOptics Letters
Volume44
Issue number7
DOIs
StatePublished - Apr 1 2019

All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics

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    Qiao, A., Tao, H., Carson, M. P., Aldrich, S. W., Thirion, L. M., Bennett, T. D., Mauro, J. C., & Yue, Y. (2019). Optical properties of a melt-quenched metal–organic framework glass. Optics Letters, 44(7), 1623-1625. https://doi.org/10.1364/OL.44.001623