Optimization of cathode catalyst layer for direct methanol fuel cells. Part I. Experimental investigation

Fuqiang Liu, Chao-yang Wang

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

The cathode catalyst layer (CL) in direct methanol fuel cells (DMFCs) has been optimized through a balance of ionomer and porosity distributions, both playing important roles in affecting proton conduction and oxygen transport through a thick CL of DMFC. The effects of fabrication procedure, ionomer content, and Pt distribution on the microstructure and performance of a cathode CL under low air flowrate are investigated. Electrochemical methods, including electrochemical impedance, cyclic votammetry and polarization curves, are used in conjunction with surface morphology characterization to correlate electrochemical characteristics with CL microstructure. CLs in the form of catalyst-coated membrane (CCM) have higher cell open circuit voltages (OCVs) and higher limiting current density; while catalyzed-diffusion-media (CDM) CLs display better performance in the moderate current density region. The CL with a composite structure, consisting both CCM and CDM, shows better performance in both kinetic and mass-transport limitation region, due to a suitable ionomer distribution across the CL. This composite cathode is further evaluated in a full DMFC and the cathode performance loss due to methanol crossover is discussed.

Original languageEnglish (US)
Pages (from-to)1417-1425
Number of pages9
JournalElectrochimica Acta
Volume52
Issue number3
DOIs
StatePublished - Nov 12 2006

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Direct methanol fuel cells (DMFC)
Cathodes
Catalysts
Ionomers
Current density
Membranes
Microstructure
Open circuit voltage
Composite structures
Surface morphology
Methanol
Protons
Mass transfer
Porosity
Polarization
Oxygen
Fabrication
Kinetics
Composite materials
Air

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Electrochemistry

Cite this

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Optimization of cathode catalyst layer for direct methanol fuel cells. Part I. Experimental investigation. / Liu, Fuqiang; Wang, Chao-yang.

In: Electrochimica Acta, Vol. 52, No. 3, 12.11.2006, p. 1417-1425.

Research output: Contribution to journalArticle

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