Organometallic and bioactive cyclophosphazenes, and the relationship to inorganic macromolecules.

Harry R. Allcock

doi:10.1080/10426508908039700

Organometallic and bioactive cyclophosphazenes, and the relationship to inorganic macromolecules.

Harry R. Allcock

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Cyclophosphazenes have two relationships to linear high polymers: first, they may function as “monomers” for polymerization to high polymers; and second, they serve as small molecule reaction and structural models for the high polymers. These principles are illustrated by the behavior of cyclophosphazenes that bear organometallic side groups, and by species that have side units that are of biomedical interest. Some emerging applications of this chemistry are also mentioned.

Original language	English (US)
Pages (from-to)	119-133
Number of pages	15
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	41
Issue number	1-2
DOIs	https://doi.org/10.1080/10426508908039700
State	Published - Jan 1 1989

All Science Journal Classification (ASJC) codes

Biochemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "Cyclophosphazenes have two relationships to linear high polymers: first, they may function as “monomers” for polymerization to high polymers; and second, they serve as small molecule reaction and structural models for the high polymers. These principles are illustrated by the behavior of cyclophosphazenes that bear organometallic side groups, and by species that have side units that are of biomedical interest. Some emerging applications of this chemistry are also mentioned.",

author = "Allcock, {Harry R.}",

note = "Funding Information: ACKNOWLEDGMENTS The work described here was supported by the U.S. National Institutes of Health (through the National Heart, Lung, and Blood Institute), Air Force Office of Scientific Research, Army Research Office, Office of Naval Research, and N.A.S.A.",

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N2 - Cyclophosphazenes have two relationships to linear high polymers: first, they may function as “monomers” for polymerization to high polymers; and second, they serve as small molecule reaction and structural models for the high polymers. These principles are illustrated by the behavior of cyclophosphazenes that bear organometallic side groups, and by species that have side units that are of biomedical interest. Some emerging applications of this chemistry are also mentioned.

AB - Cyclophosphazenes have two relationships to linear high polymers: first, they may function as “monomers” for polymerization to high polymers; and second, they serve as small molecule reaction and structural models for the high polymers. These principles are illustrated by the behavior of cyclophosphazenes that bear organometallic side groups, and by species that have side units that are of biomedical interest. Some emerging applications of this chemistry are also mentioned.

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Organometallic and bioactive cyclophosphazenes, and the relationship to inorganic macromolecules.

Abstract

All Science Journal Classification (ASJC) codes

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