Organosilicon derivatives of cyclic and high polymeric phosphazenes

Harry R. Allcock, David J. Brennan

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

A new class of compounds is reviewed, the members of which are hybrids of organosilicon and organophosphazene species. They are synthesized either by the reaction of organosilicon halides with organocopper-phosphazene intermediates, or by the interaction of organosilyl or organosiloxy Grignard reagents with chlorophosphazenes. Several of the cyclic trimeric phosphazenes prepared in this way were polymerized by heating to give linear high polymeric phosphazenes with organosilicon side groups.

Original languageEnglish (US)
Pages (from-to)231-239
Number of pages9
JournalJournal of Organometallic Chemistry
Volume341
Issue number1-3
DOIs
StatePublished - Mar 1 1988

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phosphazene
Heating
halides
reagents
Derivatives
heating
interactions

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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Organosilicon derivatives of cyclic and high polymeric phosphazenes. / Allcock, Harry R.; Brennan, David J.

In: Journal of Organometallic Chemistry, Vol. 341, No. 1-3, 01.03.1988, p. 231-239.

Research output: Contribution to journalArticle

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