Organosilylphosphazene polymers: synthesis via lithiophenoxyphosphazenes

William D. Coggio, David J. Brennan, R. Scott Archibald, Harry R. Allcock

Research output: Contribution to journalConference articlepeer-review

3 Scopus citations

Abstract

We have published several papers on the synthesis of high molecular weight polyphosphazenes that bear organosilicon or organosiloxane side groups. This work is an extension of poly(lithiophenoxy)phosphazene chemistry to include the coupling reaction between a pendent lithiophenoxy group on a phosphazene high polymer and chloroorganosilanes. In addition, a new type of reaction is reported in which the lithiophenoxy group induces the ring-opening of hexamethylcyclotrisiloxane to produce a polyphosphazene with a pendent oligosiloxy unit.

Original languageEnglish (US)
Pages (from-to)204-205
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume30
Issue number1
StatePublished - Apr 1 1989
EventPapers Presented at the Dallas, Texas Meeting - Dallas, TX, USA
Duration: Apr 9 1989Apr 14 1989

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

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