Origin of high piezoelectric response in A-site disordered morphotropic phase boundary composition of lead-free piezoelectric 0.93(Na 0.5Bi0.5)TiO3-0.07BaTiO3

Deepam Maurya, M. Murayama, A. Pramanick, W. T. Reynolds, Ke An, Shashank Priya

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Perovskite piezoelectric compositions near the morphotropic phase boundary (MPB) are known to exhibit high piezoelectric response. In lead-based ABO 3 compound with B-site disorder, the origin of this enhancement has been associated with the presence of an intermediate monoclinic/orthorhombic state that bridges the adjacent ferroelectric rhombohedral and tetragonal phases. However, the origin of high piezoelectric response in lead-free ABO 3 compounds with A-site disorder has not been conclusively established. We describe a microscopic model derived from comparative analyses of high resolution transmission electron microscopy and neutron diffraction that explains the origin of high piezoelectric response in lead-free MPB compositions of 0.93(Na0.5Bi0.5)TiO3-0. 07BaTiO3. Direct observation of nanotwins with monoclinic symmetry confirmed the presence of an intermediate bridging phase that facilitates a pathway for polarization reorientation. Monoclinic distortions of an average rhombohedral phase are attributed to localized displacements of atoms along the non-polar directions.

Original languageEnglish (US)
Article number114101
JournalJournal of Applied Physics
Issue number11
StatePublished - Mar 21 2013


All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

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