OXIDATION OF CYCLOHEXENE BY MOLECULAR OXYGEN CATALYZED BY A LAMELLAR COMPOUND OF GRAPHITE WITH MoCl//5. II. KINETICS AND MECHANISM OF CYCLOHEXENE OXIDATION.

N. I. Kovtyukhova, V. M. Belousov, Yu N. Novikov, M. E. Vol'pin

Research output: Contribution to journalArticle

Abstract

The kinetics of oxidation of cyclohexene by molecular oxygen on a lamellar compound of graphite (LCG) with MoCl//5 has been studied in chlorobenzene solution at atmospheric pressure in the temperature range 50-75 degree C. A reaction scheme has been proposed, according to which the LCG-MoCl//5 takes part in the degenerate branching stage as well as in decomposition of cyclohexenyl hydroperoxide and in chain termination. The kinetic equations obtained based on this proposed mechanism described the experimental data quite well.

Original languageEnglish (US)
Pages (from-to)310-316
Number of pages7
JournalKinetics and Catalysis
Volume28
Issue number2 pt 1
StatePublished - Mar 1 1987

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Modeling and Simulation
  • Computer Science Applications

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