OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE.

Nina Ivanivna Kovtyukhova, V. M. Belousov, G. A. Konishevskaya, Yu N. Novikov, M. E. Vol'pin

Research output: Contribution to journalArticle

Abstract

The kinetics of the decomposition of cyclohexenyl hydroperoxide (CHHP) has been studied on a graphite intercalation compound with MoCl//5 in cyclohexene solution in the temperature range 50-75 degree C. A reaction scheme has been proposed, including the participation of the catalyst in the radical decomposition of CHHP and epoxidation by it of cyclohexene. Based on the proposed scheme, kinetic equations have been obtained, which effectively represent the experimental data.

Original languageEnglish (US)
Pages (from-to)1158-1163
Number of pages6
JournalKinetics and Catalysis
Volume27
Issue number6 pt 1
StatePublished - Nov 1 1986

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Intercalation compounds
Graphite
Oxidation
Hydrogen Peroxide
Oxygen
Kinetics
Decomposition
Decompose
Epoxidation
Kinetic Equation
Catalyst
Experimental Data
Catalysts
Range of data
Temperature
cyclohexene
Participation

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Modeling and Simulation
  • Computer Science Applications

Cite this

Kovtyukhova, Nina Ivanivna ; Belousov, V. M. ; Konishevskaya, G. A. ; Novikov, Yu N. ; Vol'pin, M. E. / OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE. In: Kinetics and Catalysis. 1986 ; Vol. 27, No. 6 pt 1. pp. 1158-1163.
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abstract = "The kinetics of the decomposition of cyclohexenyl hydroperoxide (CHHP) has been studied on a graphite intercalation compound with MoCl//5 in cyclohexene solution in the temperature range 50-75 degree C. A reaction scheme has been proposed, including the participation of the catalyst in the radical decomposition of CHHP and epoxidation by it of cyclohexene. Based on the proposed scheme, kinetic equations have been obtained, which effectively represent the experimental data.",
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OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE. / Kovtyukhova, Nina Ivanivna; Belousov, V. M.; Konishevskaya, G. A.; Novikov, Yu N.; Vol'pin, M. E.

In: Kinetics and Catalysis, Vol. 27, No. 6 pt 1, 01.11.1986, p. 1158-1163.

Research output: Contribution to journalArticle

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