Oxidative dissolution under the channel leads geomorphological evolution at the shale hills catchment

Pamela L. Sullivan, Scott A. Hynek, Xin Gu, Kamini Singha, Timothy Stapler White, Nicole West, Hyojin Kim, Brian Clarke, Eric Kirby, Christopher J. Duffy, Susan Louise Brantley

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The hydrologic connectivity between hillslopes and streams impacts the geomorphological evolution of catchments. Here, we propose a conceptual model for hydrogeomorphological evolution of the Susquehanna Shale Hills Critical Zone Observatory (SSHCZO), a first-order catchment developed on shale in central Pennsylvania, U.S.A. At SSHCZO, the majority of available water (the difference between incoming meteoric water and outgoing evapotranspiration) flows laterally to the catchment outlet as interflow, while the rest is transported by regional groundwater flow. Interflow, shallow hillslope flow, is limited to the upper 5 to 8 m of highly fractured bedrock, thought to have formed during periglacial conditions in the late Pleistocene. In contrast, groundwater flowpaths are influenced by the primary permeability of the varying stratigraphic units. Both flowpaths respond to weathering-related secondary permeability.O2-rich interflow mixes with deepO2-poor groundwater under the catchment outlet at depths of 5-8 m. Penetration of this oxygenated interflow under the valley results in pyrite oxidation, release of sulfuric acid, dissolution of minerals, and weakening of bedrock. This is hypothesized to enhance channel incision and, in turn, to promote drainage of deep groundwater from the ridges. Drainage subsequently lowers the catchment water table, advancing the cascade of reactions that produce regolith. Weathering in the catchment is characterized by both sharp and diffuse reaction fronts. Relatively sharp fronts (pyrite, carbonate) mark where vertical, unsaturated flow changes to horizontal, saturated flow, while diffuse fronts (illite, chlorite, feldspar) mark where flow is largely vertical and unsaturated. According to this model, catchment morphology reflects subsurface pyrite reactions due to mixing of interflow and groundwater flow under the valley floor that ultimately results in clay weathering and regolith production nearer the land surface.

Original languageEnglish (US)
Pages (from-to)981-1026
Number of pages46
JournalAmerican Journal of Science
Volume316
Issue number10
DOIs
StatePublished - Dec 1 2016

Fingerprint

shale
dissolution
catchment
pyrite
weathering
regolith
hillslope
groundwater flow
groundwater
bedrock
observatory
drainage
permeability
valley
unsaturated flow
meteoric water
illite
sulfuric acid
chlorite
connectivity

All Science Journal Classification (ASJC) codes

  • Earth and Planetary Sciences(all)

Cite this

Sullivan, Pamela L. ; Hynek, Scott A. ; Gu, Xin ; Singha, Kamini ; White, Timothy Stapler ; West, Nicole ; Kim, Hyojin ; Clarke, Brian ; Kirby, Eric ; Duffy, Christopher J. ; Brantley, Susan Louise. / Oxidative dissolution under the channel leads geomorphological evolution at the shale hills catchment. In: American Journal of Science. 2016 ; Vol. 316, No. 10. pp. 981-1026.
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Sullivan, PL, Hynek, SA, Gu, X, Singha, K, White, TS, West, N, Kim, H, Clarke, B, Kirby, E, Duffy, CJ & Brantley, SL 2016, 'Oxidative dissolution under the channel leads geomorphological evolution at the shale hills catchment', American Journal of Science, vol. 316, no. 10, pp. 981-1026. https://doi.org/10.2475/10.2016.02

Oxidative dissolution under the channel leads geomorphological evolution at the shale hills catchment. / Sullivan, Pamela L.; Hynek, Scott A.; Gu, Xin; Singha, Kamini; White, Timothy Stapler; West, Nicole; Kim, Hyojin; Clarke, Brian; Kirby, Eric; Duffy, Christopher J.; Brantley, Susan Louise.

In: American Journal of Science, Vol. 316, No. 10, 01.12.2016, p. 981-1026.

Research output: Contribution to journalArticle

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AU - Sullivan, Pamela L.

AU - Hynek, Scott A.

AU - Gu, Xin

AU - Singha, Kamini

AU - White, Timothy Stapler

AU - West, Nicole

AU - Kim, Hyojin

AU - Clarke, Brian

AU - Kirby, Eric

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AU - Brantley, Susan Louise

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