OXIDIZED PETROLEUM FRACTIONS AS CO-SURFACTANTS AND AS FEEDSTOCKS FOR THE MANUFACTURE OF SULFONATES FOR THE TERTIARY RECOVERY OF OIL.

E. E. Klaus; J. H. Jones; R. Nagarajan; T. Ertekin; J. J. Fan; C. M. Lin; A. J. Yarzumbek; G. King

OXIDIZED PETROLEUM FRACTIONS AS CO-SURFACTANTS AND AS FEEDSTOCKS FOR THE MANUFACTURE OF SULFONATES FOR THE TERTIARY RECOVERY OF OIL.

E. E. Klaus, J. H. Jones, R. Nagarajan, T. Ertekin, J. J. Fan, C. M. Lin, A. J. Yarzumbek, G. King

Research output: Contribution to journal › Conference article › peer-review

Abstract

Pure paraffinic hydrocarbons and petroleum fractions (which may be aromatic-free) on vapor phase oxidation give an oxidized product useful as a co-surfactant and as a feedstock for the synthesis of sulfonates. The oxidations may be carried out in a simple tubular reactor using oxygen or air as the oxidant and nitrogen or steam as the reactor diluent and reaction-heat absorber. The reaction is non-catalytic and occurs readily at atmospheric pressure at temperatures ranging from 300 to 400 degree C. The oxidized products which are rich in cyclic ethers react readily with sulfur trioxide or oleum to give sulfonates as the principal products. Such sulfonates are effective surfactants in tertiary oil recovery.

Original language	English (US)
Pages (from-to)	287-292
Number of pages	6
Journal	Materials Research Bulletin
State	Published - Jan 1 1980
Event	Soc Pet Eng AIME Pap SPE Presented at SPE Int Symp on Oilfield and Geotherm Chem, 5th - Stanford Univ, Calif Duration: May 28 1980 → May 30 1980

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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title = "OXIDIZED PETROLEUM FRACTIONS AS CO-SURFACTANTS AND AS FEEDSTOCKS FOR THE MANUFACTURE OF SULFONATES FOR THE TERTIARY RECOVERY OF OIL.",

abstract = "Pure paraffinic hydrocarbons and petroleum fractions (which may be aromatic-free) on vapor phase oxidation give an oxidized product useful as a co-surfactant and as a feedstock for the synthesis of sulfonates. The oxidations may be carried out in a simple tubular reactor using oxygen or air as the oxidant and nitrogen or steam as the reactor diluent and reaction-heat absorber. The reaction is non-catalytic and occurs readily at atmospheric pressure at temperatures ranging from 300 to 400 degree C. The oxidized products which are rich in cyclic ethers react readily with sulfur trioxide or oleum to give sulfonates as the principal products. Such sulfonates are effective surfactants in tertiary oil recovery.",

author = "Klaus, {E. E.} and Jones, {J. H.} and R. Nagarajan and T. Ertekin and Fan, {J. J.} and Lin, {C. M.} and Yarzumbek, {A. J.} and G. King",

year = "1980",

month = jan,

day = "1",

language = "English (US)",

pages = "287--292",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Limited",

note = "Soc Pet Eng AIME Pap SPE Presented at SPE Int Symp on Oilfield and Geotherm Chem, 5th ; Conference date: 28-05-1980 Through 30-05-1980",

}

OXIDIZED PETROLEUM FRACTIONS AS CO-SURFACTANTS AND AS FEEDSTOCKS FOR THE MANUFACTURE OF SULFONATES FOR THE TERTIARY RECOVERY OF OIL. / Klaus, E. E.; Jones, J. H.; Nagarajan, R.; Ertekin, T.; Fan, J. J.; Lin, C. M.; Yarzumbek, A. J.; King, G.

In: Materials Research Bulletin, 01.01.1980, p. 287-292.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - OXIDIZED PETROLEUM FRACTIONS AS CO-SURFACTANTS AND AS FEEDSTOCKS FOR THE MANUFACTURE OF SULFONATES FOR THE TERTIARY RECOVERY OF OIL.

AU - Klaus, E. E.

AU - Jones, J. H.

AU - Nagarajan, R.

AU - Ertekin, T.

AU - Fan, J. J.

AU - Lin, C. M.

AU - Yarzumbek, A. J.

AU - King, G.

PY - 1980/1/1

Y1 - 1980/1/1

N2 - Pure paraffinic hydrocarbons and petroleum fractions (which may be aromatic-free) on vapor phase oxidation give an oxidized product useful as a co-surfactant and as a feedstock for the synthesis of sulfonates. The oxidations may be carried out in a simple tubular reactor using oxygen or air as the oxidant and nitrogen or steam as the reactor diluent and reaction-heat absorber. The reaction is non-catalytic and occurs readily at atmospheric pressure at temperatures ranging from 300 to 400 degree C. The oxidized products which are rich in cyclic ethers react readily with sulfur trioxide or oleum to give sulfonates as the principal products. Such sulfonates are effective surfactants in tertiary oil recovery.

AB - Pure paraffinic hydrocarbons and petroleum fractions (which may be aromatic-free) on vapor phase oxidation give an oxidized product useful as a co-surfactant and as a feedstock for the synthesis of sulfonates. The oxidations may be carried out in a simple tubular reactor using oxygen or air as the oxidant and nitrogen or steam as the reactor diluent and reaction-heat absorber. The reaction is non-catalytic and occurs readily at atmospheric pressure at temperatures ranging from 300 to 400 degree C. The oxidized products which are rich in cyclic ethers react readily with sulfur trioxide or oleum to give sulfonates as the principal products. Such sulfonates are effective surfactants in tertiary oil recovery.

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M3 - Conference article

AN - SCOPUS:0019175940

SP - 287

EP - 292

JO - Materials Research Bulletin

JF - Materials Research Bulletin

SN - 0025-5408

T2 - Soc Pet Eng AIME Pap SPE Presented at SPE Int Symp on Oilfield and Geotherm Chem, 5th

Y2 - 28 May 1980 through 30 May 1980

ER -