Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide

Louis M. Wojcinski, Michelle T. Boyer, Ayusman Sen

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Cationic palladium(II) complexes of the type [L2Pd(CH3)(CH3CN)]BF4 (L2 = 1,3-bis(diphenylphosphino)propane (Dppp) or 1,2-bis(2,5-dimethylphospholano)benzene (Me-Duphos)) were found to catalyze the alternating copolymerization of ethene, propene and cyclopentene with sulfur dioxide, as well as the terpolymerization of ethene, propene and sulfur dioxide. The resultant materials are high melting solids with an alternating alkene-SO2 structure and an exclusive head-to-tail enchainment for propene.

Original languageEnglish (US)
Pages (from-to)8-11
Number of pages4
JournalInorganica Chimica Acta
Volume270
Issue number1-2
StatePublished - Apr 2 1998

Fingerprint

Sulfur Dioxide
sulfur dioxides
Palladium
Alkenes
Sulfur dioxide
copolymerization
Copolymerization
alkenes
Olefins
Propylene
palladium
Terpolymerization
propane
Cyclopentanes
benzene
melting
Benzene
Propane
Freezing
Melting

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Wojcinski, Louis M. ; Boyer, Michelle T. ; Sen, Ayusman. / Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide. In: Inorganica Chimica Acta. 1998 ; Vol. 270, No. 1-2. pp. 8-11.
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Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide. / Wojcinski, Louis M.; Boyer, Michelle T.; Sen, Ayusman.

In: Inorganica Chimica Acta, Vol. 270, No. 1-2, 02.04.1998, p. 8-11.

Research output: Contribution to journalArticle

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