Palladium(II)-catalyzed synthesis of alternating fluoroalkene-carbon monoxide copolymers

Shahid Murtuza, Seth B. Harkins, Ayusman Sen

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The cationic palladium(II) complex [(R,R-Me-DuPHOS)Pd(Me)(CH3CN)]+BF4- (R,R-Me-DuPHOS = 1,2-bis[(2R,5A)-2,5-dimethylphospholano]benzene) was found to catalyze the perfectly alternating copolymerization of fluorinated allylbenzene derivatives with carbon monoxide, leading to functional polymers containing pendant fluorinated groups. The copolymers each exhibited relatively high hydrophobicity, as determined by goniometry. The aft-allylpentafluorobenzene-carbon monoxide copolymer was found to significantly increase the water contact angle of poly(methyl methacrylate) when blended in small amounts with the latter.

Original languageEnglish (US)
Pages (from-to)8701-8702
Number of pages2
JournalMacromolecules
Volume32
Issue number26
StatePublished - Dec 28 1999

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Palladium
Carbon Monoxide
Carbon monoxide
Copolymers
Functional polymers
Polymethyl Methacrylate
Hydrophobicity
Benzene
Polymethyl methacrylates
Copolymerization
Contact angle
Derivatives
Water
allylbenzene

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Murtuza, Shahid ; Harkins, Seth B. ; Sen, Ayusman. / Palladium(II)-catalyzed synthesis of alternating fluoroalkene-carbon monoxide copolymers. In: Macromolecules. 1999 ; Vol. 32, No. 26. pp. 8701-8702.
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Palladium(II)-catalyzed synthesis of alternating fluoroalkene-carbon monoxide copolymers. / Murtuza, Shahid; Harkins, Seth B.; Sen, Ayusman.

In: Macromolecules, Vol. 32, No. 26, 28.12.1999, p. 8701-8702.

Research output: Contribution to journalArticle

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