Performance degradation of P3HT:PCBM polymer/fullerene photovoltaic cells under gamma irradiation

A. M. Todd, T. Zhu, F. Zhang, C. U. Zhang, A. D. Berger, Jian Xu

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Organic photovoltaic cells are being considered for space applications due to the ease of fabrication, low production cost, and the potential to be used on flexible substrates. However, space-bound cells are exposed to high levels of radiation when orbiting the Earth. In this ongoing study, we examine the performance of P3HT:PCBM photovoltaic cells after exposure to gamma radiation from a cesium-137 source (662 keV). Preliminary results show degradation of the device I-V characteristics with radiation doses up to 5 krad. The integral mode time of flight (I-TOF) technique and current extraction by a linearly increasing voltage (CELIV) technique will be used to study the electron mobility and carrier lifetime properties as a function of the radiation dose. We speculate that main chain scission and reduced .-conjugation of P3HT are the dominant mechanisms responsible for performance degradation.

Original languageEnglish (US)
Title of host publication1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems
Pages103-111
Number of pages9
Volume25
Edition11
DOIs
StatePublished - Dec 1 2009
Event1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems - 216th ECS Meeting - Vienna, Austria
Duration: Oct 4 2009Oct 9 2009

Other

Other1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems - 216th ECS Meeting
CountryAustria
CityVienna
Period10/4/0910/9/09

Fingerprint

Photovoltaic cells
Fullerenes
Dosimetry
Irradiation
Degradation
Carrier lifetime
Electron mobility
Space applications
Cesium
Polymers
Gamma rays
Earth (planet)
Radiation
Fabrication
Electric potential
Substrates
Costs

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Todd, A. M., Zhu, T., Zhang, F., Zhang, C. U., Berger, A. D., & Xu, J. (2009). Performance degradation of P3HT:PCBM polymer/fullerene photovoltaic cells under gamma irradiation. In 1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems (11 ed., Vol. 25, pp. 103-111) https://doi.org/10.1149/1.3236412
Todd, A. M. ; Zhu, T. ; Zhang, F. ; Zhang, C. U. ; Berger, A. D. ; Xu, Jian. / Performance degradation of P3HT:PCBM polymer/fullerene photovoltaic cells under gamma irradiation. 1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems. Vol. 25 11. ed. 2009. pp. 103-111
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Todd, AM, Zhu, T, Zhang, F, Zhang, CU, Berger, AD & Xu, J 2009, Performance degradation of P3HT:PCBM polymer/fullerene photovoltaic cells under gamma irradiation. in 1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems. 11 edn, vol. 25, pp. 103-111, 1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems - 216th ECS Meeting, Vienna, Austria, 10/4/09. https://doi.org/10.1149/1.3236412

Performance degradation of P3HT:PCBM polymer/fullerene photovoltaic cells under gamma irradiation. / Todd, A. M.; Zhu, T.; Zhang, F.; Zhang, C. U.; Berger, A. D.; Xu, Jian.

1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems. Vol. 25 11. ed. 2009. p. 103-111.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Todd AM, Zhu T, Zhang F, Zhang CU, Berger AD, Xu J. Performance degradation of P3HT:PCBM polymer/fullerene photovoltaic cells under gamma irradiation. In 1st International Symposium on Semiconductor and Plasmonics-Active Nanostructures for Photonic Devices and Systems. 11 ed. Vol. 25. 2009. p. 103-111 https://doi.org/10.1149/1.3236412