Performance of adsorptive desulfurization over modified Y zeolites

Yu Hui Yang, Min Liu, Chunshan Song, Xin Wen Guo

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Modified Y zeolites were prepared by ion exchanging with Cu2+ and Ce3+ ions and characterized by XRF, XRD, etc. The model fuel containing several sulfur compounds (thiophene, 2-methylthiophene, 3-methylthiophene, tetrahydrothiophene and benzothiophene) in n-octane was prepared, and the adsorption effect of modified Y zeolite to the model fuel and the adsorptive selectivity for above five sulfur compounds were analyzed by total sulfur analyzer and gas chromatograph coupled with a pulsed flame photometric detector (GC-PFPD). The results showed that the CuY zeolite adsorbed more sulfur compounds than others, and the adsorptive selectivities to different sulfur compounds were consistent with the electron density of sulfur atom in compound. The steric hindrance of sulfur compound was not an important factor for its adsorption on Y zeolite.

Original languageEnglish (US)
Pages (from-to)383-387
Number of pages5
JournalShiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section)
Volume24
Issue number4
StatePublished - Aug 1 2008

Fingerprint

Zeolites
Sulfur Compounds
Sulfur compounds
Desulfurization
Sulfur
Adsorption
Thiophenes
Thiophene
Carrier concentration
Ion exchange
Gases
Ions
Detectors
Atoms

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology

Cite this

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abstract = "Modified Y zeolites were prepared by ion exchanging with Cu2+ and Ce3+ ions and characterized by XRF, XRD, etc. The model fuel containing several sulfur compounds (thiophene, 2-methylthiophene, 3-methylthiophene, tetrahydrothiophene and benzothiophene) in n-octane was prepared, and the adsorption effect of modified Y zeolite to the model fuel and the adsorptive selectivity for above five sulfur compounds were analyzed by total sulfur analyzer and gas chromatograph coupled with a pulsed flame photometric detector (GC-PFPD). The results showed that the CuY zeolite adsorbed more sulfur compounds than others, and the adsorptive selectivities to different sulfur compounds were consistent with the electron density of sulfur atom in compound. The steric hindrance of sulfur compound was not an important factor for its adsorption on Y zeolite.",
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Performance of adsorptive desulfurization over modified Y zeolites. / Yang, Yu Hui; Liu, Min; Song, Chunshan; Guo, Xin Wen.

In: Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), Vol. 24, No. 4, 01.08.2008, p. 383-387.

Research output: Contribution to journalArticle

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AU - Guo, Xin Wen

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