PH Dependence of Liquid-Liquid Phase Separation in Organic Aerosol

Delanie J. Losey, Robert G. Parker, Miriam Arak Freedman

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Abstract

Atmospheric aerosol particles influence climate through their direct and indirect effects. These impacts depend in part on the morphology of the particles, which is determined by their composition. The effect of pH on morphology was investigated using particles composed of 3-methylglutaric acid and ammonium sulfate by manipulating the starting pH of the bulk solution through the addition of aqueous sodium hydroxide. Efflorescence, deliquescence, phase separation, and mixing transitions were observed with optical microscopy. Due to changes in its protonation states, the solubility of the organic component increases with increasing pH, which shifts the location of the separation relative humidity (SRH) from 78.7% for the fully protonated acid to 63.9% for the fully deprotonated acid. Surprisingly, this shift in the SRH leads to hysteresis between the SRH and the mixing relative humidity (MRH). Particle pH has the greatest effect on phase transitions that require nucleus formation, that is, efflorescence and SRH.

Original languageEnglish (US)
Pages (from-to)3861-3865
Number of pages5
JournalJournal of Physical Chemistry Letters
Volume7
Issue number19
DOIs
StatePublished - Oct 6 2016

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Physical and Theoretical Chemistry

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