pH-responsive capsules derived from nanocrystal templating

Hongwei Duan, Min Kuang, Gang Zhang, Dayang Wang, Dirk G. Kurth, Helmuth Möhwald

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

In the current work we demonstrate a facile and versatile way to create hydrophilic polymeric capsules by integration of Au nanocrystal templating, surface-initiated atom-transfer radical polymerization, and selective chemical cross-linking of polymer shells. Capsules of the homopolymer of 2-(dimethylamino)ethyl methacrylate and its copolymers with 2-(diethylamino) ethyl methacrylate and poly(ethylene glycol) methyl ether methacrylate were constructed. They swell at low pH and shrink at high pH. On the basis of the pH sensitivity of the resulting capsules, encapsulation and release of a drug model, rhodamine 6G, were realized. Furthermore, by cleaving Au-S bonds between Au cores and polymer shells, capsules containing free Au cores were generated, paving a simple pathway to introduce more functionality to the polymeric capsules.

Original languageEnglish (US)
Pages (from-to)11495-11499
Number of pages5
JournalLangmuir
Volume21
Issue number24
DOIs
StatePublished - Nov 22 2005

Fingerprint

capsules
Nanocrystals
Capsules
nanocrystals
Atom transfer radical polymerization
Polymers
Homopolymerization
Encapsulation
Polyethylene glycols
Ethers
Copolymers
Methyl Ethers
Methacrylates
polymers
rhodamine
glycols
ethers
copolymers
drugs
ethylene

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Duan, H., Kuang, M., Zhang, G., Wang, D., Kurth, D. G., & Möhwald, H. (2005). pH-responsive capsules derived from nanocrystal templating. Langmuir, 21(24), 11495-11499. https://doi.org/10.1021/la051638x
Duan, Hongwei ; Kuang, Min ; Zhang, Gang ; Wang, Dayang ; Kurth, Dirk G. ; Möhwald, Helmuth. / pH-responsive capsules derived from nanocrystal templating. In: Langmuir. 2005 ; Vol. 21, No. 24. pp. 11495-11499.
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Duan, H, Kuang, M, Zhang, G, Wang, D, Kurth, DG & Möhwald, H 2005, 'pH-responsive capsules derived from nanocrystal templating', Langmuir, vol. 21, no. 24, pp. 11495-11499. https://doi.org/10.1021/la051638x

pH-responsive capsules derived from nanocrystal templating. / Duan, Hongwei; Kuang, Min; Zhang, Gang; Wang, Dayang; Kurth, Dirk G.; Möhwald, Helmuth.

In: Langmuir, Vol. 21, No. 24, 22.11.2005, p. 11495-11499.

Research output: Contribution to journalArticle

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Duan H, Kuang M, Zhang G, Wang D, Kurth DG, Möhwald H. pH-responsive capsules derived from nanocrystal templating. Langmuir. 2005 Nov 22;21(24):11495-11499. https://doi.org/10.1021/la051638x