PHASE EQUILIBRIA AND STRUCTURAL CHEMISTRY IN TERNARY SYSTEMS: TRANSITION METAL-BORON-NITROGEN.

I. Smid; P. Rogl

PHASE EQUILIBRIA AND STRUCTURAL CHEMISTRY IN TERNARY SYSTEMS: TRANSITION METAL-BORON-NITROGEN.

I. Smid, P. Rogl

Engineering Science and Mechanics

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

7 Scopus citations

Abstract

The phase equilibria in the ternary systems Fe-B-N, Co-B-N and Ni-B-N have been established from X-ray powder diffraction data and isothermal sections at 900 degree C and 1 atm Ar have been constructed. In all three systems the binary transition metal borides form two-phase equilibria with hexagonal boronnitride. The iron-boron binary system has been reinvestigated by means of X-ray powder, metallographic and melting point analysis. 'FeB//2' and 'Fe//3B' are not stable in thermodynamic equilibrium and 'FeB//1//9' rather represents a solid solution phase of iron in beta -rh boron than a binary compound. A complete constitutional T-X diagram is presented.

Original language	English (US)
Title of host publication	Institute of Physics Conference Series
Pages	249-257
Number of pages	9
Edition	75
State	Published - 1986

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)

Fingerprint Dive into the research topics of 'PHASE EQUILIBRIA AND STRUCTURAL CHEMISTRY IN TERNARY SYSTEMS: TRANSITION METAL-BORON-NITROGEN.'. Together they form a unique fingerprint.

Cite this

@inproceedings{8357395a6e35421eab5f1c8fa852a481,

title = "PHASE EQUILIBRIA AND STRUCTURAL CHEMISTRY IN TERNARY SYSTEMS: TRANSITION METAL-BORON-NITROGEN.",

abstract = "The phase equilibria in the ternary systems Fe-B-N, Co-B-N and Ni-B-N have been established from X-ray powder diffraction data and isothermal sections at 900 degree C and 1 atm Ar have been constructed. In all three systems the binary transition metal borides form two-phase equilibria with hexagonal boronnitride. The iron-boron binary system has been reinvestigated by means of X-ray powder, metallographic and melting point analysis. 'FeB//2' and 'Fe//3B' are not stable in thermodynamic equilibrium and 'FeB//1//9' rather represents a solid solution phase of iron in beta -rh boron than a binary compound. A complete constitutional T-X diagram is presented.",

author = "I. Smid and P. Rogl",

year = "1986",

language = "English (US)",

isbn = "0854981667",

pages = "249--257",

booktitle = "Institute of Physics Conference Series",

edition = "75",

}

TY - GEN

T1 - PHASE EQUILIBRIA AND STRUCTURAL CHEMISTRY IN TERNARY SYSTEMS

T2 - TRANSITION METAL-BORON-NITROGEN.

AU - Smid, I.

AU - Rogl, P.

PY - 1986

Y1 - 1986

N2 - The phase equilibria in the ternary systems Fe-B-N, Co-B-N and Ni-B-N have been established from X-ray powder diffraction data and isothermal sections at 900 degree C and 1 atm Ar have been constructed. In all three systems the binary transition metal borides form two-phase equilibria with hexagonal boronnitride. The iron-boron binary system has been reinvestigated by means of X-ray powder, metallographic and melting point analysis. 'FeB//2' and 'Fe//3B' are not stable in thermodynamic equilibrium and 'FeB//1//9' rather represents a solid solution phase of iron in beta -rh boron than a binary compound. A complete constitutional T-X diagram is presented.

AB - The phase equilibria in the ternary systems Fe-B-N, Co-B-N and Ni-B-N have been established from X-ray powder diffraction data and isothermal sections at 900 degree C and 1 atm Ar have been constructed. In all three systems the binary transition metal borides form two-phase equilibria with hexagonal boronnitride. The iron-boron binary system has been reinvestigated by means of X-ray powder, metallographic and melting point analysis. 'FeB//2' and 'Fe//3B' are not stable in thermodynamic equilibrium and 'FeB//1//9' rather represents a solid solution phase of iron in beta -rh boron than a binary compound. A complete constitutional T-X diagram is presented.

UR - http://www.scopus.com/inward/record.url?scp=0022957942&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022957942&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:0022957942

SN - 0854981667

SP - 249

EP - 257

BT - Institute of Physics Conference Series

ER -