Phase field modeling of the tetragonal-to-monoclinic phase transformation in zirconia

Mahmood Mamivand, Mohsen Asle Zaeem, Haitham El Kadiri, Long-qing Chen

Research output: Contribution to journalArticle

58 Citations (Scopus)

Abstract

The allotropic phase transformation in zirconia from the tetragonal to monoclinic double lattices is known to occur by a martensitic twinning mechanism which shows a complex dependence on temperature, stress and environment. This paper is concerned with the development of a phase field model which accounts for the main metallurgical mechanisms governing this martensitic transition. The symmetry reduction and orientation relationship between the parent and product phases were simulated using several non-conserved order parameters representing different transformation paths. Inhomogeneous and anisotropic elastic properties were considered to determine the resultant elastic stresses. Governing equations of the tetragonal-to-monoclinic transformation were solved in a finite element framework under a variety of initial and boundary conditions. It was shown that applying different initial conditions, such as seed embryo or random, did not change the twinning patterns or the final volume fractions of the parent and product phases after the relaxation period. On the other hand, enforcing different boundary conditions resulted in completely different twinning patterns and phase volume fractions. The model was able to predict both the "V" shape morphology of twinning and the surface stress relief with "gable roof" patterns, which were observed by transmission electron microscopy and atomic force microscopy to be characteristic of the tetragonal-to-monoclinic transition.

Original languageEnglish (US)
Pages (from-to)5223-5235
Number of pages13
JournalActa Materialia
Volume61
Issue number14
DOIs
StatePublished - Jan 1 2013

Fingerprint

Twinning
Zirconia
Phase transitions
Volume fraction
Boundary conditions
Stress relief
Crystal lattices
Roofs
Seed
Atomic force microscopy
Transmission electron microscopy
zirconium oxide
Temperature

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

Cite this

Mamivand, Mahmood ; Zaeem, Mohsen Asle ; Kadiri, Haitham El ; Chen, Long-qing. / Phase field modeling of the tetragonal-to-monoclinic phase transformation in zirconia. In: Acta Materialia. 2013 ; Vol. 61, No. 14. pp. 5223-5235.
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Phase field modeling of the tetragonal-to-monoclinic phase transformation in zirconia. / Mamivand, Mahmood; Zaeem, Mohsen Asle; Kadiri, Haitham El; Chen, Long-qing.

In: Acta Materialia, Vol. 61, No. 14, 01.01.2013, p. 5223-5235.

Research output: Contribution to journalArticle

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