Phenylphosphonic acid functionalized poly[aryloxyphosphazenes]

Harry R. Allcock, Michael A. Hofmann, Catherine M. Ambler, Robert V. Morford

Research output: Contribution to journalArticlepeer-review

85 Scopus citations

Abstract

A method for the synthesis of phenylphosphonic acid functionalized poly[aryloxyphos-phazenes] is described. Diphenyl chlorophosphate was used as the phosphonating agent and was allowed to react with lithio-functionalized aryloxyphosphazenes, followed by treatment with aqueous sodium hydroxide. Subsequent acidification with aqueous hydrochloric acid yielded phenylphosphonic acid functionalized poly[aryloxyphosphazenes]. These polymers are candidates for use as proton-conducting membranes in fuel cells.

Original languageEnglish (US)
Pages (from-to)3484-3489
Number of pages6
JournalMacromolecules
Volume35
Issue number9
DOIs
StatePublished - Apr 23 2002

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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