Phosphorus and phosphorus-nitrogen doped carbon nanotubes for ultrasensitive and selective molecular detection

Eduardo Cruz-Silva, Florentino Lopez-Urias, Emilio Munoz-Sandoval, Bobby G. Sumpter, Humberto Terrones, Jean Christophe Charlier, Vincent Meunier, Mauricio Terrones Maldonado

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

A first-principles approach is used to establish that substitutional phosphorus atoms within carbon nanotubes strongly modify the chemical properties of the surface, thus creating highly localized sites with specific affinity towards acceptor molecules. Phosphorus-nitrogen co-dopants within the tubes have a similar effect for acceptor molecules, but the P-N bond can also accept charge, resulting in affinity towards donor molecules. This molecular selectivity is illustrated in CO and NH3 adsorbed on PN-doped nanotubes, O2 on P-doped nanotubes, and NO2 and SO 2 on both P- and PN-doped nanotubes. The adsorption of different chemical species onto the doped nanotubes modifies the dopant-induced localized states, which subsequently alter the electronic conductance. Although SO 2 and CO adsorptions cause minor shifts in electronic conductance, NH3, NO2, and O2 adsorptions induce the suppression of a conductance dip. Conversely, the adsorption of NO2 on PN-doped nanotubes is accompanied with the appearance of an additional dip in conductance, correlated with a shift of the existing ones. Overall these changes in electric conductance provide an efficient way to detect selectively the presence of specific molecules. Additionally, the high oxidation potential of the P-doped nanotubes makes them good candidates for electrode materials in hydrogen fuel cells.

Original languageEnglish (US)
Pages (from-to)1008-1013
Number of pages6
JournalNanoscale
Volume3
Issue number3
DOIs
StatePublished - Mar 1 2011

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Carbon Nanotubes
Phosphorus
Nanotubes
Carbon nanotubes
Nitrogen
Adsorption
Molecules
Carbon Monoxide
Electric conductance
Doping (additives)
Hydrogen fuels
Chemical properties
Fuel cells
Atoms
Oxidation
Electrodes

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Cruz-Silva, E., Lopez-Urias, F., Munoz-Sandoval, E., Sumpter, B. G., Terrones, H., Charlier, J. C., ... Terrones Maldonado, M. (2011). Phosphorus and phosphorus-nitrogen doped carbon nanotubes for ultrasensitive and selective molecular detection. Nanoscale, 3(3), 1008-1013. https://doi.org/10.1039/c0nr00519c
Cruz-Silva, Eduardo ; Lopez-Urias, Florentino ; Munoz-Sandoval, Emilio ; Sumpter, Bobby G. ; Terrones, Humberto ; Charlier, Jean Christophe ; Meunier, Vincent ; Terrones Maldonado, Mauricio. / Phosphorus and phosphorus-nitrogen doped carbon nanotubes for ultrasensitive and selective molecular detection. In: Nanoscale. 2011 ; Vol. 3, No. 3. pp. 1008-1013.
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Cruz-Silva, E, Lopez-Urias, F, Munoz-Sandoval, E, Sumpter, BG, Terrones, H, Charlier, JC, Meunier, V & Terrones Maldonado, M 2011, 'Phosphorus and phosphorus-nitrogen doped carbon nanotubes for ultrasensitive and selective molecular detection', Nanoscale, vol. 3, no. 3, pp. 1008-1013. https://doi.org/10.1039/c0nr00519c

Phosphorus and phosphorus-nitrogen doped carbon nanotubes for ultrasensitive and selective molecular detection. / Cruz-Silva, Eduardo; Lopez-Urias, Florentino; Munoz-Sandoval, Emilio; Sumpter, Bobby G.; Terrones, Humberto; Charlier, Jean Christophe; Meunier, Vincent; Terrones Maldonado, Mauricio.

In: Nanoscale, Vol. 3, No. 3, 01.03.2011, p. 1008-1013.

Research output: Contribution to journalArticle

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Cruz-Silva E, Lopez-Urias F, Munoz-Sandoval E, Sumpter BG, Terrones H, Charlier JC et al. Phosphorus and phosphorus-nitrogen doped carbon nanotubes for ultrasensitive and selective molecular detection. Nanoscale. 2011 Mar 1;3(3):1008-1013. https://doi.org/10.1039/c0nr00519c