Photochemical production of oligothiophene and polythiophene micropatterns from 2,5-diiodothiophene on Au in UHV

Guangming Liu, Sudarshan Natarajan, Seong Kim

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Fabrication of oligothiophene and polythiophene micropatterns is demonstrated by photochemical reactions of 2,5-diiodothiophene adsorbed on an Au coated Si wafer under UHV conditions. For patterning, a TEM grid is utilized as a model stencil mask. Fluorescence microscopic analysis shows that polymer microstructures with good pattern fidelity are attained over a large area. RAIRS and NEXAFS analyses indicate that the electronic and molecular structures of the produced polymer are similar to those of chemically synthesized polythiophene. The structural defects of the photochemically produced polymer are negligible. The present procedure provides a very efficient strategy for growth and patterning of conjugated polymer microstructures with high quality in one step.

Original languageEnglish (US)
JournalSurface Science
Volume592
Issue number1-3
DOIs
StatePublished - Nov 1 2005

Fingerprint

Polymers
polymers
Microstructure
Photochemical reactions
Conjugated polymers
Molecular structure
microstructure
Electronic structure
Masks
Fluorescence
photochemical reactions
Transmission electron microscopy
Fabrication
Defects
molecular structure
masks
grids
wafers
electronic structure
fluorescence

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

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Photochemical production of oligothiophene and polythiophene micropatterns from 2,5-diiodothiophene on Au in UHV. / Liu, Guangming; Natarajan, Sudarshan; Kim, Seong.

In: Surface Science, Vol. 592, No. 1-3, 01.11.2005.

Research output: Contribution to journalArticle

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