Platinum(II) catalysed selective remote oxidation of unactivated C-H bonds in aliphatic carboxylic acids

Lien Chung Kao; Ayusman Sen

doi:10.1039/C39910001242

Platinum(II) catalysed selective remote oxidation of unactivated C-H bonds in aliphatic carboxylic acids

Lien Chung Kao, Ayusman Sen

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Abstract

Platinum(II) ion, in the presence of platinum(IV), is found to catalyse the hydroxylation of unactivated C-H bonds of aliphatic carboxylic acids in water with the following order of reactivity: α-C-H << β-C-H < γ-C-H ≥ δ-C-H ≈ ε-C-H.

Original language	English (US)
Pages (from-to)	1242-1243
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39910001242
State	Published - Dec 1 1991

All Science Journal Classification (ASJC) codes

Molecular Medicine

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title = "Platinum(II) catalysed selective remote oxidation of unactivated C-H bonds in aliphatic carboxylic acids",

abstract = "Platinum(II) ion, in the presence of platinum(IV), is found to catalyse the hydroxylation of unactivated C-H bonds of aliphatic carboxylic acids in water with the following order of reactivity: α-C-H << β-C-H < γ-C-H ≥ δ-C-H ≈ ε-C-H.",

author = "Kao, {Lien Chung} and Ayusman Sen",

year = "1991",

month = dec,

day = "1",

doi = "10.1039/C39910001242",

language = "English (US)",

pages = "1242--1243",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "18",

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T1 - Platinum(II) catalysed selective remote oxidation of unactivated C-H bonds in aliphatic carboxylic acids

AU - Kao, Lien Chung

AU - Sen, Ayusman

PY - 1991/12/1

Y1 - 1991/12/1

N2 - Platinum(II) ion, in the presence of platinum(IV), is found to catalyse the hydroxylation of unactivated C-H bonds of aliphatic carboxylic acids in water with the following order of reactivity: α-C-H << β-C-H < γ-C-H ≥ δ-C-H ≈ ε-C-H.

AB - Platinum(II) ion, in the presence of platinum(IV), is found to catalyse the hydroxylation of unactivated C-H bonds of aliphatic carboxylic acids in water with the following order of reactivity: α-C-H << β-C-H < γ-C-H ≥ δ-C-H ≈ ε-C-H.

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DO - 10.1039/C39910001242

M3 - Article

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 18

ER -

Platinum(II) catalysed selective remote oxidation of unactivated C-H bonds in aliphatic carboxylic acids

Abstract

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