Poly(acrylonitrile-co-vinylcatecholborane): A new precursor for carbon containing B/C, B/N and B/O species

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Abstract

This paper describes a new PAN copolymer, poly(acrylonitrile-co-vinylcatecholborane), which is a precursor for carbon material containing B/C, B/N and B/O species in its molecular structures. Vinylcatecholborane, containing an appropriate protecting group in the borane moiety, can be copolymerized with acrylonitrile to high molecular weight copolymers under free radical polymerization conditions. The copolymers are processible by solution and melt methods. From 11B NMR studies, a clear B-N complex was formed in poly(acrylonitrile-co-vinylcatecholborane) copolymer. The carbonation and oxidative studies of poly(acrylnitrile-co-vinylcatecholborane) indicate effective interconversions of copolymers to various graphite-like structures containing B/C, B/N and B/O species, which show significantly higher oxidative stability than pure carbon material obtained from PAN under the same conditions.

Original languageEnglish (US)
Pages (from-to)595-600
Number of pages6
JournalCarbon
Volume34
Issue number5
DOIs
StatePublished - Jan 1 1996

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Carbon
Copolymers
Boranes
Acrylonitrile
Carbonation
Graphite
Free radical polymerization
Molecular structure
Molecular weight
Nuclear magnetic resonance
polyacrylonitrile

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

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title = "Poly(acrylonitrile-co-vinylcatecholborane): A new precursor for carbon containing B/C, B/N and B/O species",
abstract = "This paper describes a new PAN copolymer, poly(acrylonitrile-co-vinylcatecholborane), which is a precursor for carbon material containing B/C, B/N and B/O species in its molecular structures. Vinylcatecholborane, containing an appropriate protecting group in the borane moiety, can be copolymerized with acrylonitrile to high molecular weight copolymers under free radical polymerization conditions. The copolymers are processible by solution and melt methods. From 11B NMR studies, a clear B-N complex was formed in poly(acrylonitrile-co-vinylcatecholborane) copolymer. The carbonation and oxidative studies of poly(acrylnitrile-co-vinylcatecholborane) indicate effective interconversions of copolymers to various graphite-like structures containing B/C, B/N and B/O species, which show significantly higher oxidative stability than pure carbon material obtained from PAN under the same conditions.",
author = "R. Hu and Tze-chiang Chung",
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Poly(acrylonitrile-co-vinylcatecholborane) : A new precursor for carbon containing B/C, B/N and B/O species. / Hu, R.; Chung, Tze-chiang.

In: Carbon, Vol. 34, No. 5, 01.01.1996, p. 595-600.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Poly(acrylonitrile-co-vinylcatecholborane)

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AU - Hu, R.

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N2 - This paper describes a new PAN copolymer, poly(acrylonitrile-co-vinylcatecholborane), which is a precursor for carbon material containing B/C, B/N and B/O species in its molecular structures. Vinylcatecholborane, containing an appropriate protecting group in the borane moiety, can be copolymerized with acrylonitrile to high molecular weight copolymers under free radical polymerization conditions. The copolymers are processible by solution and melt methods. From 11B NMR studies, a clear B-N complex was formed in poly(acrylonitrile-co-vinylcatecholborane) copolymer. The carbonation and oxidative studies of poly(acrylnitrile-co-vinylcatecholborane) indicate effective interconversions of copolymers to various graphite-like structures containing B/C, B/N and B/O species, which show significantly higher oxidative stability than pure carbon material obtained from PAN under the same conditions.

AB - This paper describes a new PAN copolymer, poly(acrylonitrile-co-vinylcatecholborane), which is a precursor for carbon material containing B/C, B/N and B/O species in its molecular structures. Vinylcatecholborane, containing an appropriate protecting group in the borane moiety, can be copolymerized with acrylonitrile to high molecular weight copolymers under free radical polymerization conditions. The copolymers are processible by solution and melt methods. From 11B NMR studies, a clear B-N complex was formed in poly(acrylonitrile-co-vinylcatecholborane) copolymer. The carbonation and oxidative studies of poly(acrylnitrile-co-vinylcatecholborane) indicate effective interconversions of copolymers to various graphite-like structures containing B/C, B/N and B/O species, which show significantly higher oxidative stability than pure carbon material obtained from PAN under the same conditions.

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