Polymer brushes

Research output: Contribution to journalArticlepeer-review

1621 Scopus citations

Abstract

Polymers attached by one end to an interface at relatively high coverage stretch away from the interface to avoid overlapping, forming a polymer "brush." This simple picture may serve as the basis for models hi diverse interfacial systems in polymer science, such as polymeric surfactants, stabilized suspensions of colloidal particles, and structures formed by block copolymers. The structure and dynamics of polymer brushes have been the subject of considerable theoretical and experimental activity hi recent years. An account is given of recent advances hi theoretical understanding of stretched polymers at interfaces, and the diverse experimental probes of systems modeled by brushes are briefly reviewed.

Original languageEnglish (US)
Pages (from-to)905-914
Number of pages10
JournalScience
Volume251
Issue number4996
DOIs
StatePublished - Feb 22 1991

All Science Journal Classification (ASJC) codes

  • General

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