Polymer laminates for high energy density and low loss

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

In this study, we investigate the effect of added interfaces on the dielectric and breakdown response of polyvinylidene fluoride polymer (PVDF). Multilayer laminates (1 through 4 layers) of PVDF are fabricated using hot pressing. A series of electrical characterization techniques including high voltage breakdown, dielectric spectroscopy and impedance spectroscopy, show the effect of interfacial elements on dielectric breakdown strength (displaying an 18% increase from a 1-layer to 3-layer structure) and dielectric permittivity (increasing 10% from 1- to 4-layers). Equivalent circuit modeling of impedance data is used to characterize the effect of laminated interfaces at low frequencies (10 mHz) and elevated temperatures (70 °C). Results suggest capacitive circuit elements in addition to a Debye like bulk model are necessary to describe space charge polarizations observed in multilayered structures. Better understanding the effect of added interfaces on charge transport in all organic laminates will provide insight into conduction through organic dielectric media, and offer insight into improving energy density and mitigating loss in high energy storage applications.

Original languageEnglish (US)
Title of host publication2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages457-460
Number of pages4
ISBN (Electronic)9781509046546
DOIs
StatePublished - Dec 15 2016
Event2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016 - Toronto, Canada
Duration: Oct 16 2016Oct 19 2016

Publication series

NameAnnual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP
Volume2016-December
ISSN (Print)0084-9162

Other

Other2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016
CountryCanada
CityToronto
Period10/16/1610/19/16

Fingerprint

Laminates
Polymers
Electric breakdown
Dielectric spectroscopy
Hot pressing
Electric space charge
Equivalent circuits
Energy storage
Charge transfer
Multilayers
Permittivity
Spectroscopy
Polarization
Networks (circuits)
Temperature
polyvinylidene fluoride

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Electrical and Electronic Engineering

Cite this

Vecchio, M. A., Ounaies, Z., Lanagan, M. T., & Barhoumi Ep Meddeb, A. (2016). Polymer laminates for high energy density and low loss. In 2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016 (pp. 457-460). [7785648] (Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP; Vol. 2016-December). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/CEIDP.2016.7785648
Vecchio, Michael A. ; Ounaies, Zoubeida ; Lanagan, Michael T. ; Barhoumi Ep Meddeb, Amira. / Polymer laminates for high energy density and low loss. 2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016. Institute of Electrical and Electronics Engineers Inc., 2016. pp. 457-460 (Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP).
@inproceedings{7dc8b821c9ea4dea8064b5f3e038d870,
title = "Polymer laminates for high energy density and low loss",
abstract = "In this study, we investigate the effect of added interfaces on the dielectric and breakdown response of polyvinylidene fluoride polymer (PVDF). Multilayer laminates (1 through 4 layers) of PVDF are fabricated using hot pressing. A series of electrical characterization techniques including high voltage breakdown, dielectric spectroscopy and impedance spectroscopy, show the effect of interfacial elements on dielectric breakdown strength (displaying an 18{\%} increase from a 1-layer to 3-layer structure) and dielectric permittivity (increasing 10{\%} from 1- to 4-layers). Equivalent circuit modeling of impedance data is used to characterize the effect of laminated interfaces at low frequencies (10 mHz) and elevated temperatures (70 °C). Results suggest capacitive circuit elements in addition to a Debye like bulk model are necessary to describe space charge polarizations observed in multilayered structures. Better understanding the effect of added interfaces on charge transport in all organic laminates will provide insight into conduction through organic dielectric media, and offer insight into improving energy density and mitigating loss in high energy storage applications.",
author = "Vecchio, {Michael A.} and Zoubeida Ounaies and Lanagan, {Michael T.} and {Barhoumi Ep Meddeb}, Amira",
year = "2016",
month = "12",
day = "15",
doi = "10.1109/CEIDP.2016.7785648",
language = "English (US)",
series = "Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP",
publisher = "Institute of Electrical and Electronics Engineers Inc.",
pages = "457--460",
booktitle = "2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016",
address = "United States",

}

Vecchio, MA, Ounaies, Z, Lanagan, MT & Barhoumi Ep Meddeb, A 2016, Polymer laminates for high energy density and low loss. in 2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016., 7785648, Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP, vol. 2016-December, Institute of Electrical and Electronics Engineers Inc., pp. 457-460, 2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016, Toronto, Canada, 10/16/16. https://doi.org/10.1109/CEIDP.2016.7785648

Polymer laminates for high energy density and low loss. / Vecchio, Michael A.; Ounaies, Zoubeida; Lanagan, Michael T.; Barhoumi Ep Meddeb, Amira.

2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016. Institute of Electrical and Electronics Engineers Inc., 2016. p. 457-460 7785648 (Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP; Vol. 2016-December).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

TY - GEN

T1 - Polymer laminates for high energy density and low loss

AU - Vecchio, Michael A.

AU - Ounaies, Zoubeida

AU - Lanagan, Michael T.

AU - Barhoumi Ep Meddeb, Amira

PY - 2016/12/15

Y1 - 2016/12/15

N2 - In this study, we investigate the effect of added interfaces on the dielectric and breakdown response of polyvinylidene fluoride polymer (PVDF). Multilayer laminates (1 through 4 layers) of PVDF are fabricated using hot pressing. A series of electrical characterization techniques including high voltage breakdown, dielectric spectroscopy and impedance spectroscopy, show the effect of interfacial elements on dielectric breakdown strength (displaying an 18% increase from a 1-layer to 3-layer structure) and dielectric permittivity (increasing 10% from 1- to 4-layers). Equivalent circuit modeling of impedance data is used to characterize the effect of laminated interfaces at low frequencies (10 mHz) and elevated temperatures (70 °C). Results suggest capacitive circuit elements in addition to a Debye like bulk model are necessary to describe space charge polarizations observed in multilayered structures. Better understanding the effect of added interfaces on charge transport in all organic laminates will provide insight into conduction through organic dielectric media, and offer insight into improving energy density and mitigating loss in high energy storage applications.

AB - In this study, we investigate the effect of added interfaces on the dielectric and breakdown response of polyvinylidene fluoride polymer (PVDF). Multilayer laminates (1 through 4 layers) of PVDF are fabricated using hot pressing. A series of electrical characterization techniques including high voltage breakdown, dielectric spectroscopy and impedance spectroscopy, show the effect of interfacial elements on dielectric breakdown strength (displaying an 18% increase from a 1-layer to 3-layer structure) and dielectric permittivity (increasing 10% from 1- to 4-layers). Equivalent circuit modeling of impedance data is used to characterize the effect of laminated interfaces at low frequencies (10 mHz) and elevated temperatures (70 °C). Results suggest capacitive circuit elements in addition to a Debye like bulk model are necessary to describe space charge polarizations observed in multilayered structures. Better understanding the effect of added interfaces on charge transport in all organic laminates will provide insight into conduction through organic dielectric media, and offer insight into improving energy density and mitigating loss in high energy storage applications.

UR - http://www.scopus.com/inward/record.url?scp=85009786684&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85009786684&partnerID=8YFLogxK

U2 - 10.1109/CEIDP.2016.7785648

DO - 10.1109/CEIDP.2016.7785648

M3 - Conference contribution

AN - SCOPUS:85009786684

T3 - Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP

SP - 457

EP - 460

BT - 2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016

PB - Institute of Electrical and Electronics Engineers Inc.

ER -

Vecchio MA, Ounaies Z, Lanagan MT, Barhoumi Ep Meddeb A. Polymer laminates for high energy density and low loss. In 2016 IEEE Conference on Electrical Insulation and Dielectric Phenomena, CEIDP 2016. Institute of Electrical and Electronics Engineers Inc. 2016. p. 457-460. 7785648. (Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP). https://doi.org/10.1109/CEIDP.2016.7785648