Polymer nanocomposites using zinc aluminum and magnesium aluminum oleate layered double hydroxides

Effects of the polymeric compatibilizer and of composition on the thermal and fire properties of PP/LDH nanocomposites

Charles Manzi-Nshuti, Ponusa Songtipya, Evangelos Manias, Maria Del Mar Jimenez Gasco, Jeanne M. Hossenlopp, Charles A. Wilkie

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

A series of five oleate-containing layered double hydroxides with varied ratios of zinc to magnesium, i.e., with the general formula Zn2-yMgyAl(OH)6 [CH3(CH2)7CH{double bond, long}CH(CH2)7COO]·nH2O, were synthesized and used to prepare nanocomposites of polypropylene (PP). The nanomaterials were characterized by elemental analysis, attenuated total reflection-infrared spectroscopy (ATR-IR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA), while the composites were characterized by XRD, TGA, transmission electron microscopy (TEM) and cone calorimetry. The zinc-containing LDH showed better dispersion in the polymer at the micrometer level than did the magnesium-containing LDH while both are equally well-dispersed at the nanometer level. The magnesium-containing composites led to more thermally stable systems in TGA experiments, while the zinc systems gave greater reductions in heat release rate during combustion. Dispersion was also affected by the amount of PP-g-MA which was present. More PP-g-MA gave better dispersion and a significantly reduced peak heat release rate, i.e., enhanced fire performance.

Original languageEnglish (US)
Pages (from-to)2042-2054
Number of pages13
JournalPolymer Degradation and Stability
Volume94
Issue number11
DOIs
StatePublished - Nov 1 2009

Fingerprint

Hydroxides
Compatibilizers
Polypropylenes
Oleic Acid
Aluminum
polypropylene
Magnesium
hydroxides
Thermogravimetric analysis
magnesium
Zinc
Nanocomposites
nanocomposites
Polymers
Fires
thermodynamic properties
zinc
aluminum
polymers
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Mechanics of Materials
  • Polymers and Plastics
  • Materials Chemistry

Cite this

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title = "Polymer nanocomposites using zinc aluminum and magnesium aluminum oleate layered double hydroxides: Effects of the polymeric compatibilizer and of composition on the thermal and fire properties of PP/LDH nanocomposites",
abstract = "A series of five oleate-containing layered double hydroxides with varied ratios of zinc to magnesium, i.e., with the general formula Zn2-yMgyAl(OH)6 [CH3(CH2)7CH{double bond, long}CH(CH2)7COO]·nH2O, were synthesized and used to prepare nanocomposites of polypropylene (PP). The nanomaterials were characterized by elemental analysis, attenuated total reflection-infrared spectroscopy (ATR-IR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA), while the composites were characterized by XRD, TGA, transmission electron microscopy (TEM) and cone calorimetry. The zinc-containing LDH showed better dispersion in the polymer at the micrometer level than did the magnesium-containing LDH while both are equally well-dispersed at the nanometer level. The magnesium-containing composites led to more thermally stable systems in TGA experiments, while the zinc systems gave greater reductions in heat release rate during combustion. Dispersion was also affected by the amount of PP-g-MA which was present. More PP-g-MA gave better dispersion and a significantly reduced peak heat release rate, i.e., enhanced fire performance.",
author = "Charles Manzi-Nshuti and Ponusa Songtipya and Evangelos Manias and {Jimenez Gasco}, {Maria Del Mar} and Hossenlopp, {Jeanne M.} and Wilkie, {Charles A.}",
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T1 - Polymer nanocomposites using zinc aluminum and magnesium aluminum oleate layered double hydroxides

T2 - Effects of the polymeric compatibilizer and of composition on the thermal and fire properties of PP/LDH nanocomposites

AU - Manzi-Nshuti, Charles

AU - Songtipya, Ponusa

AU - Manias, Evangelos

AU - Jimenez Gasco, Maria Del Mar

AU - Hossenlopp, Jeanne M.

AU - Wilkie, Charles A.

PY - 2009/11/1

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N2 - A series of five oleate-containing layered double hydroxides with varied ratios of zinc to magnesium, i.e., with the general formula Zn2-yMgyAl(OH)6 [CH3(CH2)7CH{double bond, long}CH(CH2)7COO]·nH2O, were synthesized and used to prepare nanocomposites of polypropylene (PP). The nanomaterials were characterized by elemental analysis, attenuated total reflection-infrared spectroscopy (ATR-IR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA), while the composites were characterized by XRD, TGA, transmission electron microscopy (TEM) and cone calorimetry. The zinc-containing LDH showed better dispersion in the polymer at the micrometer level than did the magnesium-containing LDH while both are equally well-dispersed at the nanometer level. The magnesium-containing composites led to more thermally stable systems in TGA experiments, while the zinc systems gave greater reductions in heat release rate during combustion. Dispersion was also affected by the amount of PP-g-MA which was present. More PP-g-MA gave better dispersion and a significantly reduced peak heat release rate, i.e., enhanced fire performance.

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