Polymer Nanocomposites with Interpenetrating Gradient Structure Exhibiting Ultrahigh Discharge Efficiency and Energy Density

Jianyong Jiang, Zhonghui Shen, Xingke Cai, Jianfeng Qian, Zhenkang Dan, Yuanhua Lin, Bilu Liu, Ce Wen Nan, Longqing Chen, Yang Shen

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Poly(vinylidene fluoride) (PVDF) based polymer nanocomposites with high-permittivity nanofillers exhibit outstanding dielectric energy storage performance due to their high dielectric permittivities and breakdown strength. However, their discharge efficiency is relatively low (usually lower than 70%), which limits their practical applications. Here, polymer nanocomposites with a novel interpenetrating gradient structure are designed and demonstrated by cofilling a PVDF matrix with barium zirconate titanate nanofibers and hexagonal boron nitride nanosheets via modified nonequilibrium processing. The interpenetrating gradient structure is highly effective in breaking the trade-off between discharge energy density and efficiency of the corresponding nanocomposite, as indicated by the concomitantly enhanced discharge energy density (U e ≈ 23.4 J cm −3 ) and discharge efficiency (η ≈ 83%). The superior performance is primarily attributed to the rational distribution of nanofillers in the polymer matrix, which raises the height of the potential barrier for charge injection at the dielectric/electrode interface, suppresses electric conduction and contributes to enhanced apparent breakdown strength. Meanwhile, the gradient configuration allows higher volume fraction of high-permittivity nanofillers without compromising the breakdown strength, leading to higher electric polarization compared with the random configuration. This work provides new opportunities to PVDF-based polymer nanocomposites with high energy density and discharge efficiency for capacitive energy storage applications.

Original languageEnglish (US)
Article number1803411
JournalAdvanced Energy Materials
Volume9
Issue number15
DOIs
StatePublished - Apr 18 2019

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Nanocomposites
Polymers
Permittivity
Energy storage
Barium zirconate
Charge injection
Boron nitride
Nanosheets
Nanofibers
Polymer matrix
Volume fraction
Polarization
Electrodes
Processing
polyvinylidene fluoride

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Jiang, Jianyong ; Shen, Zhonghui ; Cai, Xingke ; Qian, Jianfeng ; Dan, Zhenkang ; Lin, Yuanhua ; Liu, Bilu ; Nan, Ce Wen ; Chen, Longqing ; Shen, Yang. / Polymer Nanocomposites with Interpenetrating Gradient Structure Exhibiting Ultrahigh Discharge Efficiency and Energy Density. In: Advanced Energy Materials. 2019 ; Vol. 9, No. 15.
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Polymer Nanocomposites with Interpenetrating Gradient Structure Exhibiting Ultrahigh Discharge Efficiency and Energy Density. / Jiang, Jianyong; Shen, Zhonghui; Cai, Xingke; Qian, Jianfeng; Dan, Zhenkang; Lin, Yuanhua; Liu, Bilu; Nan, Ce Wen; Chen, Longqing; Shen, Yang.

In: Advanced Energy Materials, Vol. 9, No. 15, 1803411, 18.04.2019.

Research output: Contribution to journalArticle

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T1 - Polymer Nanocomposites with Interpenetrating Gradient Structure Exhibiting Ultrahigh Discharge Efficiency and Energy Density

AU - Jiang, Jianyong

AU - Shen, Zhonghui

AU - Cai, Xingke

AU - Qian, Jianfeng

AU - Dan, Zhenkang

AU - Lin, Yuanhua

AU - Liu, Bilu

AU - Nan, Ce Wen

AU - Chen, Longqing

AU - Shen, Yang

PY - 2019/4/18

Y1 - 2019/4/18

N2 - Poly(vinylidene fluoride) (PVDF) based polymer nanocomposites with high-permittivity nanofillers exhibit outstanding dielectric energy storage performance due to their high dielectric permittivities and breakdown strength. However, their discharge efficiency is relatively low (usually lower than 70%), which limits their practical applications. Here, polymer nanocomposites with a novel interpenetrating gradient structure are designed and demonstrated by cofilling a PVDF matrix with barium zirconate titanate nanofibers and hexagonal boron nitride nanosheets via modified nonequilibrium processing. The interpenetrating gradient structure is highly effective in breaking the trade-off between discharge energy density and efficiency of the corresponding nanocomposite, as indicated by the concomitantly enhanced discharge energy density (U e ≈ 23.4 J cm −3 ) and discharge efficiency (η ≈ 83%). The superior performance is primarily attributed to the rational distribution of nanofillers in the polymer matrix, which raises the height of the potential barrier for charge injection at the dielectric/electrode interface, suppresses electric conduction and contributes to enhanced apparent breakdown strength. Meanwhile, the gradient configuration allows higher volume fraction of high-permittivity nanofillers without compromising the breakdown strength, leading to higher electric polarization compared with the random configuration. This work provides new opportunities to PVDF-based polymer nanocomposites with high energy density and discharge efficiency for capacitive energy storage applications.

AB - Poly(vinylidene fluoride) (PVDF) based polymer nanocomposites with high-permittivity nanofillers exhibit outstanding dielectric energy storage performance due to their high dielectric permittivities and breakdown strength. However, their discharge efficiency is relatively low (usually lower than 70%), which limits their practical applications. Here, polymer nanocomposites with a novel interpenetrating gradient structure are designed and demonstrated by cofilling a PVDF matrix with barium zirconate titanate nanofibers and hexagonal boron nitride nanosheets via modified nonequilibrium processing. The interpenetrating gradient structure is highly effective in breaking the trade-off between discharge energy density and efficiency of the corresponding nanocomposite, as indicated by the concomitantly enhanced discharge energy density (U e ≈ 23.4 J cm −3 ) and discharge efficiency (η ≈ 83%). The superior performance is primarily attributed to the rational distribution of nanofillers in the polymer matrix, which raises the height of the potential barrier for charge injection at the dielectric/electrode interface, suppresses electric conduction and contributes to enhanced apparent breakdown strength. Meanwhile, the gradient configuration allows higher volume fraction of high-permittivity nanofillers without compromising the breakdown strength, leading to higher electric polarization compared with the random configuration. This work provides new opportunities to PVDF-based polymer nanocomposites with high energy density and discharge efficiency for capacitive energy storage applications.

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