Polymerization and Copolymerization of Phenylhalogenocyclotriphosphazenes

H. R. Allcock, G. Y. Moore

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

N3P3F5Ph (III) homopolymerizes when heated, but gem-N3P3Cl4Ph2 (IV), gem-N3P3F4Ph2 (V), non-gem-N3P3Cl3Ph3 (VI), gem-N3P3Cl2Ph4 (VII), N3P3ClPh5 (VIII), and (NPPh2)3 (IX) do not. However, compounds III, IV, V, and VI copolymerize with (NPCl2)3 (II), whereas VII, VIII, and IX inhibit the polymerization of II. The polymers were derivatized by placement of halogen with CF3CH2O-, or piperidino groups, and the properties of these thermoplastics and elastomers were examined. The mechanistic implications of the results are discussed.

Original languageEnglish (US)
Pages (from-to)377-382
Number of pages6
JournalMacromolecules
Volume8
Issue number4
DOIs
StatePublished - Jul 1 1975

Fingerprint

Gems
Copolymerization
Polymerization
Elastomers
Halogens
Thermoplastics
Polymers

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

@article{25811da8d2454822a83a296d69f9c954,
title = "Polymerization and Copolymerization of Phenylhalogenocyclotriphosphazenes",
abstract = "N3P3F5Ph (III) homopolymerizes when heated, but gem-N3P3Cl4Ph2 (IV), gem-N3P3F4Ph2 (V), non-gem-N3P3Cl3Ph3 (VI), gem-N3P3Cl2Ph4 (VII), N3P3ClPh5 (VIII), and (NPPh2)3 (IX) do not. However, compounds III, IV, V, and VI copolymerize with (NPCl2)3 (II), whereas VII, VIII, and IX inhibit the polymerization of II. The polymers were derivatized by placement of halogen with CF3CH2O-, or piperidino groups, and the properties of these thermoplastics and elastomers were examined. The mechanistic implications of the results are discussed.",
author = "Allcock, {H. R.} and Moore, {G. Y.}",
year = "1975",
month = "7",
day = "1",
doi = "10.1021/ma60046a001",
language = "English (US)",
volume = "8",
pages = "377--382",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "4",

}

Polymerization and Copolymerization of Phenylhalogenocyclotriphosphazenes. / Allcock, H. R.; Moore, G. Y.

In: Macromolecules, Vol. 8, No. 4, 01.07.1975, p. 377-382.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Polymerization and Copolymerization of Phenylhalogenocyclotriphosphazenes

AU - Allcock, H. R.

AU - Moore, G. Y.

PY - 1975/7/1

Y1 - 1975/7/1

N2 - N3P3F5Ph (III) homopolymerizes when heated, but gem-N3P3Cl4Ph2 (IV), gem-N3P3F4Ph2 (V), non-gem-N3P3Cl3Ph3 (VI), gem-N3P3Cl2Ph4 (VII), N3P3ClPh5 (VIII), and (NPPh2)3 (IX) do not. However, compounds III, IV, V, and VI copolymerize with (NPCl2)3 (II), whereas VII, VIII, and IX inhibit the polymerization of II. The polymers were derivatized by placement of halogen with CF3CH2O-, or piperidino groups, and the properties of these thermoplastics and elastomers were examined. The mechanistic implications of the results are discussed.

AB - N3P3F5Ph (III) homopolymerizes when heated, but gem-N3P3Cl4Ph2 (IV), gem-N3P3F4Ph2 (V), non-gem-N3P3Cl3Ph3 (VI), gem-N3P3Cl2Ph4 (VII), N3P3ClPh5 (VIII), and (NPPh2)3 (IX) do not. However, compounds III, IV, V, and VI copolymerize with (NPCl2)3 (II), whereas VII, VIII, and IX inhibit the polymerization of II. The polymers were derivatized by placement of halogen with CF3CH2O-, or piperidino groups, and the properties of these thermoplastics and elastomers were examined. The mechanistic implications of the results are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0000159904&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000159904&partnerID=8YFLogxK

U2 - 10.1021/ma60046a001

DO - 10.1021/ma60046a001

M3 - Article

AN - SCOPUS:0000159904

VL - 8

SP - 377

EP - 382

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 4

ER -